玻璃成型超冷液体中合作性波动的普遍性
Jürgen E K Schawe1, Kylian Hallavant2, Antonella Esposito2
1Laboratory of Metal Physics and Technology, Department of Materials, ETH Zurich, 8093 Zurich, Switzerland.
The journal of physical chemistry letters
|November 17, 2025
概括
无形玻璃中合作重排区域 (CRR) 的大小显示了各种材料的普遍温度依赖性. 这一发现将CRR规模与玻璃过渡和放松动态联系起来.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 物理化学 物理化学
背景情况:
- 无形玻璃通过快速融冷却形成,抑制结晶.
- 玻璃化温度与冷却速度和融粘度相关.
- 分子移动性,动态异质性和合作重排区 (CRR) 支配玻璃的特性.
研究的目的:
- 研究CRR的平均相关长度 (ξ) 的温度依赖性.
- 检查这种关系在不同的玻璃形成 (有机,聚合物,化物,金属).
- 专注于具有脆性指数 (m) ≥40的玻璃成型器.
主要方法:
- 对CRR的平均相关长度 (ξ) 的分析.
- 研究相对于玻璃过渡温度 (Tg) 的温度依赖性.
- 在不同类型的材料中比较结果.
主要成果:
- 观察到XX的物质独立变化与减少的相互温度 (Tg/T).
- 证明了 ξ ((Tg/T) 是研究的玻璃制造商的通用函数.
- 发现了 ξ 与α-放松的激活能量之间的直接比例.
结论:
- 在各种玻璃成型材料中,CRR大小的温度依赖是普遍的.
- 风险投资额的大小与α-放松的激活能量密切相关.
- 在宏观玻璃成形运动参数和CRR动态之间建立了关系.
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