同时去除SO2和NOx从低温下用水合石灰烧结烟气中的SO2和NOx
Shuhua Geng1, Guoqiang Gao2, Tiehua Cao3
1State Key Laboratory of Advanced Refractories & Shanghai Key Laboratory of Advanced Ferro Metallurgy & School of Materials Science and Engineering, Shanghai University, Shanghai, 200444, China. shgeng@i.shu.edu.cn.
Environmental science and pollution research international
|November 18, 2025
概括
本研究探讨使用氧化从工业烟气中去除二氧化硫 (SO2) 和氧化 (NOx). 它详细介绍了吸附剂特性如何变化,影响超低排放标准下的污染物去除效率.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 控制工业污染 控制工业污染
背景情况:
- 烧结烟气处理对于钢铁行业至关重要.
- 将二氧化硫 (SO2) 和氧化 (NOx) 减少到极低的排放水平具有重大挑战.
研究的目的:
- 研究各种参数对使用氧化 (Ca(OH) 2) 去除 SO2 和 NOx 的影响.
- 阐明硫酸盐和酸盐产品在吸附过程中的生长和相位演变机制.
主要方法:
- 在不同温度,湿度和气体度 (SO2,NO2,CO2,O2) 下对吸附的系统研究.
- 吸附剂特性 (BET表面积,孔腔体积,孔腔大小) 和产品阶段演变的分析.
主要成果:
- 硫酸盐形成形成了密集的表面层,减少了吸附剂的表面积和孔积,导致疲劳.
- 脱离二氧化 (NO2) 的产品显示向内增长,形成表面孔和裂.
- 澄清了在超低排放水平下增加氧化消耗和碳酸形成的机制.
结论:
- 吸附剂失活机制对于SO2和NO2不同.
- 了解这些机制是优化烟气处理以达到严格的环境标准的关键.
更多相关视频
相关概念视频
Sample Preparation for Analysis: Advanced Techniques
1.2K
Accurate analysis of complex samples often requires advanced preparation techniques to achieve reliable and reproducible results. Samples containing inorganic or organic materials can be challenging to dissolve or decompose effectively. Standard sample preparation methods include acid digestion, fusion, dry ashing, and wet digestion.
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
Acid digestion with strong acids is commonly used to dissolve inorganic materials that are insoluble (do not dissolve) in water. This method can be useful for...
1.2K
Hydration of Cement
770
Hydration of cement is a chemical reaction between cement particles and water. This process occurs primarily through two mechanisms: through-solution and topochemical. In the through-solution process, anhydrous compounds dissolve into their constituents, hydrates form in the solution, and then precipitate from the supersaturated solution. The topochemical process involves solid-state reactions at the cement particle surface. The through-solution process dominates the topochemical process at the...
770
Sublimation
4.7K
Sublimation is the direct transformation of a solid to a gaseous state. For instance, at standard pressure and room temperature, solid carbon dioxide sublimes to gaseous carbon dioxide. The phase diagram depicts the conditions required for sublimation. This process occurs at the solid-gas phase boundary and is not observed above the triple point of the substance. The reverse of sublimation is called deposition, where a gaseous substance condenses directly into a solid. Sublimation and...
4.7K
Strength and Heat of Hydration
631
The hydration of cement is an exothermic reaction in which heat is generated as cement hydrates. This heat of hydration is critical to cement's strength development. The rate at which this heat is generated affects the temperature rise, with a majority of the heat being released early in the hydration process, half within the first three days, and about 75% within the first week.
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
631


