从α相聚乙烯化物中产生的拓结构诱导的压电
Tao Yang1, Weili Deng1, Xin Chen2
1Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, 610031, P. R. China.
研究人员在非极性聚乙烯化物 (PVDF) 聚合物中创建了一种新的梅隆类拓极性结构. 这一突破使得以前被禁止的特性,如非极性聚合物相中的压电.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物科学 聚合物科学
- 凝聚物质物理学 凝聚物质物理学
背景情况:
- 拓极性结构提供了独特的新兴现象,这种现象在传统的铁电材料中并不存在.
- 与铁电氧化物相比,铁电聚合物中的拓结构很少见.
研究的目的:
- 为了证明在非极性α相聚乙烯化物 (PVDF) 中创建了类似于梅龙的拓极性结构.
- 调查这种新型拓结构的形成机制和特性.
主要方法:
- 结合实验技术,包括凯尔文探针力显微镜,第二波生成和介电光谱.
- 计算方法来揭示扭曲的片的形成和由此产生的拓结构.
- 直接和反向的压电测量.
主要成果:
- 在α相PVDF中成功创建了一个类似于meron的拓极结构.
- 证明了拓结构中的应变促进的非零极化.
- 在拓α相PVDF中确认了压电性,并将其与极化和拓特征相关联.
结论:
- 本文介绍了一种用于在非极性铁电聚合物中创建极性拓结构的新方法.
- 这些发现允许在非极性聚合物相中诱导对称性禁止的特性,例如压电性.
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