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对于水性电池的MOF/COF集成战略:最近的进展,修改方法和未来的指导方针

Zihao Jiang¹, Mingkun Xie², Qingyuan Ma³

¹Sustainable Energy and Environment Thrust, Function Hub, The Hong Kong University of Science and Technology (Guangzhou), Guangzhou 511400, China.

Dalton transactions (Cambridge, England : 2003)

|November 20, 2025

概括

金属有机框架 (MOFs) 和共价有机框架 (COFs) 通过解决树突成长和提高效率来增强水性离子电池 (AZIBs). 本综述详细介绍了下一代储能系统的MOF/COF战略.

科学领域:

材料科学材料科学材料科学
电化学电化学电化学
储能储能储能储能储能储能

背景情况:

水性离子电池 (AZIB) 显示了可持续能源储存的前景.
关键的挑战包括树石的形成,腐蚀和低库伦比效率 (CE).
金属有机框架 (MOF) 和共价有机框架 (COF) 提供可调节的特性来克服这些限制.

研究的目的:

对AZIBs的MOF和COF的最新进展进行审查.
探索MOF/COF结构和组件修改如何提高电池性能.
为设计未来基于MOF/COF的能源存储建立一个框架.

主要方法:

在AZIB中对MOF和COF应用的文献审查.
对内在MOF/COF结构变化的分析 (孔径大小,功能组,金属种类).
对MOF/COF集成到电池组件 (分离器,电极,电解质) 的检查.

主要成果:

在AZIB中,MOF和COF有效地减轻了树的生长和腐蚀.
调整MOF/COF结构并将其纳入电池组件可以显著提高性能.
成功的策略可以提高coulombic效率和电池的整体稳定性.

结论:

MOF和COF对于推进AZIB技术至关重要.
战略设计和MOF/COF的应用为实际储能提供了解决方案.
本综述为开发高性能MOF/COF基AZIB提供了指导方针.

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