在城市化河流中追踪微塑料和酸盐的溶解有机物代理:光和分子洞察力
Yuanyuan Cao1, Yang Liu1, Shibao Liu1
1Key Laboratory of Groundwater Conservation of MWR, Key Laboratory of Groundwater Circulation and Environmental Evolution of MOE, School of Water Resources and Environment, China University of Geosciences Beijing, Beijing 100083, China.
Journal of hazardous materials
|November 20, 2025
概括
溶解有机物 (DOM) 的比例有效地追踪河流中的微塑料 (MP) 和酸盐 (PAE). 表示废水的C2/C1 DOM代理可靠地与这些新出现的污染物相关,有助于对生态风险进行评估.
科学领域:
- 环境化学环境化学
- 水质监测 水质监测
- 污染物水文学污染物水文学
背景情况:
- 新兴污染物如微塑料 (MP) 和酸盐 (PAE) 在水生环境中普遍存在.
- 需要有效的追踪代理来了解MP和PAE的发生和影响.
研究的目的:
- 建议和验证溶解有机物 (DOM) 代理用于在城市化河流中追踪MP和PAE.
- 确定C2/C1比率作为通用废水代理,并评估其与污染物水平的相关性.
主要方法:
- 光减去以分析DOM组合 (类似蛋白质的C2,类似的C1).
- 主要组件分析以确定DOM来源 (陆地与人为).
- 在DOM代理和MP/PAE度之间进行相关性分析和多变量线性回归.
主要成果:
- C2/C1比率有效地表明废水排放,增加C2和减少C1.
- DOM代理 (C2/C1,C2%,BIX) 与MP和PAE有很强的相关性.
- 微塑料和低分子量PAE与蛋白质丰富,贫DOM (高C2 / C1) 相关,这表明生态风险更高.
结论:
- 在城市河流中,DOM代理,特别是C2/C1比率,可以作为MP和PAE的可靠和成本有效的追踪器.
- 这种方法为评估生态风险和对塑料衍生污染物进行有针对性的监测提供了有价值的选工具.
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