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Updated: Jan 10, 2026

Designed for Molecular Recycling: A Lignin-Derived Semi-aromatic Biobased Polymer
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Designed for Molecular Recycling: A Lignin-Derived Semi-aromatic Biobased Polymer

Published on: November 30, 2020

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可回收聚的多功能平台:替代性聚合化 (或它们的衍生物) 与循环无水化

Xun Zhang1,2, Chengjian Zhang1,2, Xinghong Zhang1,2

  • 1State Key Laboratory of Biobased Transportation Fuel Technology, International Research Center for X Polymers, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China.

Accounts of chemical research
|November 21, 2025
PubMed
概括

从可再生资源中合成的化学可回收聚烯为化石塑料提供了一个可持续的替代品. 这种新方法可以实现高效的闭环回收和可调节的降解,解决塑料污染问题.

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The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
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Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...
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Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
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