一种阻燃的局部高度电解质,用于高压离子电池
Luo Zhang1,2, Haodong Zhao3, Donglai Xiao4
1Information Materials and Device Applications Key Laboratory of Sichuan Provincial Universities, Chengdu University of Information Technology, Chengdu 610225, China.
Nanoscale
|November 21, 2025
概括
这项研究引入了用于离子电池 (LIB) 的不可燃电解质,通过取代挥发性溶剂来提高安全性. 新设计确保在高压应用中稳定的性能,这对于电动汽车和电网存储至关重要.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 电池技术 电池技术
背景情况:
- 离子电池 (LIB) 对电动汽车和电网存储至关重要,但由于易燃的电解质,它们面临安全挑战.
- 高能量密度的LIBs需要具有更宽的电化学窗口和更好的稳定性的电解质.
研究的目的:
- 开发一种非易燃的高压电解质,使LIB更安全,更稳定.
- 用新型电解质研究电池电极上的保护界面的形成.
主要方法:
- 使用LiTFSI,化乙烯碳酸盐 (FEC) 和化以太 (TTE) 制备局部高度电解质 (LHCE).
- 电化学表征包括电化学窗户测试.
- 组装和循环NCM811Gr全细胞来评估性能和稳定性.
主要成果:
- LHCE 显示了 5.5 V 的电化学窗口,并显著降低了可燃性.
- 协同效应导致了强大的富含LiF的SEI和CEI层,防止了电极降解.
- NCM811Gr电池在4.5V的电压下表现出极好的循环性 (在200个循环中损失8%以下的电容),并具有很高的库伦比效率 (99.9%).
结论:
- 拟议的非易燃LHCE为提高高压LIB的安全性和性能提供了一个有希望的解决方案.
- 这种电解质设计为开发下一代储能系统提供了途径.
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