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Polymer Classification: Crystallinity01:21

Polymer Classification: Crystallinity

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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
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Intrinsically Disordered Proteins02:18

Intrinsically Disordered Proteins

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Intrinsically disordered proteins are a group of proteins that do not fold into specific three-dimensional structures. Their structural flexibility allows them to complement ordered proteins to perform functions that are inaccessible to rigid structures. They are more common in eukaryotes than prokaryotes and may either be exclusively intrinsically disordered or hybrid proteins, consisting of a mix of ordered and disordered regions. The absence of a rigid structure in these proteins can be...
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Intrinsically Disordered Proteins02:18

Intrinsically Disordered Proteins

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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Polymer Classification: Architecture01:14

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Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
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Ferromagnetism01:31

Ferromagnetism

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Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
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Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules
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陀螺形:一种新的功能性无序材料类.

Mathias Casiulis1,2, Aaron Shih1,3, Stefano Martiniani1,2,3,4

  • 1New York University, Center for Soft Matter Research, Department of Physics, New York, New York 10003, USA.

Physical review letters
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概括

我们介绍了陀螺形态,新型无序材料具有独特的旋转顺序. 这些结构允许优越的低指数对比带间隙用于光学应用.

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Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
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科学领域:

  • 材料科学 材料科学 材料科学
  • 凝聚物质物理学 凝聚物质物理学
  • 光子学是指光子学中的一个方面.

背景情况:

  • 无序的材料往往缺乏可预测的特性.
  • 对先进的应用来说,控制无序系统中的秩序至关重要.

研究的目的:

  • 引入一种新的功能相关的无序材料类:陀螺形态.
  • 调查它们独特的混合液态转换失调和准远程旋转顺序的组合.
  • 探索它们在创建低指数对比度同位素带间隙方面的潜力.

主要方法:

  • 使用光谱优化生成2D和3D陀螺形状.
  • 分析旋转和转移顺序的结构因子.
  • 数字模拟 (合二极点近似) 用于带间隙形成.
  • 分析有效介质理论和散射无平均值路径估计.

主要成果:

  • 陀螺形体表现出强大的离散旋转顺序,没有远程转换顺序.
  • 在形成同otropic 带间隙方面优于准晶体,隐形超均性和Vogel 螺旋.
  • 在2D中为标量波和向量波实现低指数对比带间隙.
  • 在3D中打开完整的同otropic带间隙.
  • 多角形可实现多频段间隙,用于精细的光学属性控制.

结论:

  • 陀螺形体代表了设计功能性无序材料的新范式.
  • 它们独特的结构为光子应用提供了显著的优势,特别是在带隙工程中.
  • 多重体形的发展使得对光学属性的前所未有的控制.