从废弃 W-Mo 合金中分离 W 和 Mo,采用集成超声波酸洗 - 洗 - 溶剂提取工艺
Chaoya Shi1, Bingbing Liu2, Zeyi Xiao1
1School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001 Henan, PR China.
Ultrasonics sonochemistry
|November 23, 2025
概括
这项研究引入了一种高效的超声波辅助水电金工艺,用于从废料合金中分离 (W) 和 (Mo). 综合方法显著提高了关键金属回收的回收率和纯度.
科学领域:
- 金工程 金工程 金工程
- 材料科学 材料科学 材料科学
- 水电金术是指用水电金术进行金术.
背景情况:
- - (W-Mo) 合金在航空航天和国防方面至关重要.
- 废弃的W-Mo合金由于合金结构和化学惰性而带来了回收挑战.
- 传统的洗过程对W和Mo的回收效率很低.
研究的目的:
- 开发一种高效的综合工艺,从废弃 W-Mo 合金中分离和.
- 研究超声波辅助漏的应用,以提高回收效率.
- 为了优化W和Mo的分离,使用酸液,液和溶剂提取.
主要方法:
- 超声波辅助的酸水,然后是性水.
- 对W和Mo溶解行为的热力学计算.
- 四个阶段的N1923溶剂提取用于W-Mo分离.
- 电化学分析和材料表征,以阐明机制.
主要成果:
- 超声波辅助浸出减少了浸出时间,提高了效率.
- 酸液选择性地保留了W在残留物中,同时溶解了Mo.
- 性液将剩余的 W 和 Mo 转移到溶液中.
- 溶剂提取实现了高纯度的分离,在精炼中,W和Mo度分别为0.02g/L和20.39g/L.
结论:
- 集成的超声波辅助水电金工艺是有效的W-Mo从废料合金的分离.
- 超声波化增强了质量转移和反应动力学,提高了漏效率.
- 该战略为重点金属回收和环境保护提供了一种可持续的方法.
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