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Updated: Jan 10, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-phosphinetriyltripiperidine]}palladium Under Mild Reaction Conditions
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Published on: March 20, 2014

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关于PhI (OAc) 2在CMD途径中的介导的分子内C (sp3) -H激活作用的计算研究

Peng-Yu Liu1,2, Yuehui Xu1,3, Xin Peng1,3

  • 1State Key Laboratory of Fine Chemicals, Ningbo Institute of Dalian University of Technology, No.26 Yucai Road, Ningbo 315016, China.

The Journal of organic chemistry
|November 24, 2025
PubMed
概括

本研究详细介绍了使用基二酸盐的C(sp3) -H键的协同化-脱化 (CMD). 计算模拟揭示了一种新的催化途径,比传统方法提供了更高的效率.

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All ortho–para directors, excluding halogens, are activating groups. These groups donate electrons to the ring, making the ring carbons electron-rich. Consequently, the reactivity of the aromatic ring towards electrophilic substitution increases. For instance, the nitration of anisole is about 10,000 times faster than the nitration of benzene. The electron-donating effect of the methoxy group in anisole activates the ortho and para positions on the ring and stabilizes the corresponding...
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