在纳米级界面特征引起的合体和多相系统中的动态动力交叉
Dhiraj Nandyala1, Carlos E Colosqui1,2,3
1Mechanical Engineering Department, Stony Brook University, Stony Brook, NY 11794, USA. carlos.colosqui@stonybrook.edu.
Soft matter
|November 25, 2025
概括
体和多相系统从动态过渡到接近平衡的缓慢动态. 这种交叉,由纳米级接口特征驱动,使可编程的运输控制在不同的系统.
科学领域:
- 合体和表面科学科学
- 软物质物理学 软物质物理学
- 化学工程是化学工程的组成部分.
背景情况:
- 多相系统表现出由经典运输方程控制的动态模式.
- 在平衡点附近,发生过渡到异常缓慢的放松 (运动状态).
- 这种交叉与来自纳米级接口特征的能量障碍有关.
研究的目的:
- 审查一个统一的框架,用于预测和控制动态到动态模式交叉.
- 突出纳米尺度特征在运输工程中的表面积与系统维度比的作用.
- 探索可编程运输控制在合体和多相系统中的策略.
主要方法:
- 综述跨多种多相系统的实验观测结果.
- 对描述模式交叉的理论框架的分析.
- 检查纳米级界面特征对运输特性的影响.
主要成果:
- 在多相系统中实验性地观察到从动态到动力学行为的政权交叉.
- 接口上的纳米尺度特征带来的大型能量障碍导致了这种交叉.
- 纳米尺寸表面积与微观尺寸的比例是交通工程的一个关键参数.
结论:
- 有一个统一的框架来预测和控制动态运动交叉.
- 利用动态-动力学双重性提供可编程的运输控制.
- 工程界面特征提供了一种手段,以量身定制的运输特性在合体和多相系统.
相关概念视频
Colloids and Suspensions
3.0K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
3.0K
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
745
Various dissolution theories provide insight into the factors that influence the dissolution rate. Danckwerts' Model suggests that turbulence, rather than a stagnant layer, characterizes the dissolution medium at the solid-liquid interface. In this model, the agitated solvent contains macroscopic packets that move to the interface via eddy currents, facilitating the absorption and delivery of the drug to the bulk solution. The regular replenishment of solvent packets maintains the...
745
Intermolecular Forces in Solutions
38.5K
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
38.5K
Intermolecular Forces
68.8K
Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen...
68.8K
Basic Postulates of Kinetic Molecular Theory: Particle Size, Energy, and Collision
37.3K
The ideal-gas equation, which is empirical, describes the behavior of gases by establishing relationships between their macroscopic properties. For example, Charles’ law states that volume and temperature are directly related. Gases, therefore, expand when heated at constant pressure. Although gas laws explain how the macroscopic properties change relative to one another, it does not explain the rationale behind it.
37.3K
Colloids
20.5K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
20.5K


