玻璃酸盐中异常的断裂行为是由压力诱导的分子重组促进的
Jet Lem1,2, Eric R Sung1, Alexei A Maznev1
1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139.
概括
酸玻璃在高拉伸率下表现出独特的断裂行为. 压力诱导的原子重新排列使它能够承受极端的拉力应力,揭示了内在的硬化机制.
科学领域:
- 材料科学 材料科学 材料科学
- 固体机械学 固体机械学
- 玻璃科学 玻璃科学
背景情况:
- 基于的玻璃在许多领域都至关重要.
- 对于极端应用来说,了解它们在高应变率下的机械行为至关重要.
- 酸玻璃是这一类的关键材料.
研究的目的:
- 为了研究玻璃酸盐的高应变率断裂行为.
- 在动态应力下识别其机械反应背后的机制.
- 探索无形材料中潜在的硬化机制.
主要方法:
- 在光学上生成收的表面声波 (SAW).
- 控制振幅SAW的应用以诱导高张力率 (10^8s^-1).
- 分析断裂模式,拉曼光谱和冲击样本的纳米痕.
主要成果:
- 酸玻璃可以承受高达11GPa的拉伸应力.
- 应力值为6GPa,可以引发表面破裂.
- 在8GPa的第二个值大大降低了骨折的概率.
- 观察到和原子拓和协调的显著变化.
结论:
- 压力诱导的分子重组作为一种内在的强化机制.
- 这种机制在动态应变下增强玻璃酸盐玻璃的断裂性.
- 这些发现为设计适应极端条件的坚固无形材料提供了洞察力.
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