纳米级观测 (II) 通过绿色生硫酸盐封存
Khondaker M N Alam1, Junho Han1,2, Bojeong Kim3
1Department of Earth & Environmental Sciences, Rutgers University, 101 Warren Street, Newark, New Jersey 07102, United States.
概括
绿色生 (GR) 是一种反应性矿物质,通过形成新的层,并随着时间的推移将其纳入其散装结构,从而将 (Ni-II) 封存起来. 这一过程影响了微量金属在减少环境中的流动性.
科学领域:
- 地质化学 地质化学
- 矿物学是什么?矿物学是什么?
- 环境科学 环境科学
背景情况:
- 绿色生 (GR) 是一种混合价值的铁层双氧化物 (Fe-(II) -Fe-(III) -LDH) 矿物.
- 在减少地化学环境中发现GR,并显示出高吸附和氧化还原活性.
研究的目的:
- 以纳米级分辨率检查GR粒子的形态和化学.
- 研究Ni-(II) aq与GR随着时间的推移 (1小时到3个月) 的相互作用.
主要方法:
- 扫描传输电子显微镜与能量分散式X射线光谱学 (STEM-EDXS) 相结合.
- 顺序的提取. 顺序的提取.
主要成果:
- 最初在第一天内在GR颗粒边缘上形成了Ni-(II) /Fe-(II) -Fe-(III) -LDH混合轮.
- 3个月后,尽管吸收增加了,但Ni-(II) 被扣留在GR散装中,由更薄的边缘和更少的表面Ni-(II) 表示.
- 根据STEM-EDXS和提取数据显示,Ni-II) 随着时间的推移从表面再分配到散装.
结论:
- 在衰老过程中,GR在粒子表面发生化学和结构变化.
- 在几天到几周的时间尺度上,Ni-(II) 酸盐重新分配到GR散体中.
- 这些发现为微量金属的分离和在减少地化学系统中的移动性提供了机械的见解.
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