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Updated: Jan 10, 2026

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在光照射下氧化结晶和固定的合

Jielong Cao1,2,3,4, Qingze Chen1,2,3,4, Xun Liu1,2,3,4

  • 1State Key Laboratory of Advanced Environmental Technology, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China. chenqingze@gig.ac.cn.

Chemical communications (Cambridge, England)
|November 26, 2025
PubMed
概括

(II) 的光化学氧化有助于通过吸附和共沉降去除 (I). (I) 进一步稳定氧化物,增强其自身的固定性.

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Radical Oxidation of Allylic and Benzylic Alcohols01:21

Radical Oxidation of Allylic and Benzylic Alcohols

Activated manganese(IV) oxide can selectively oxidize allylic and benzylic alcohols via a radical intermediate mechanism. Primary allylic alcohols are oxidized to aldehydes, while secondary allylic alcohols yield ketones. The redox reaction of potassium permanganate with an Mn(II) salt such as manganese sulfate (under either alkaline or acidic conditions), followed by thorough drying, yields the oxidizing agent: activated MnO2. While MnO2 is insoluble in the solvents used for the reaction, the...
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