自愈火灾防治和灭火水凝来自carboxymethyl纤维素修饰的两共聚物
1College of Chemical Engineering and Materials, Shandong University of Aeronautics, Binzhou 256600, China.
Gels (Basel, Switzerland)
|November 26, 2025
概括
为了采矿安全,开发了一种新的自我愈合的水凝,碳甲基纤维素修饰的两性聚合物. 这种先进的凝具有防火和灭火性能,增强了地下操作安全性.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 采矿工程 采矿工程 采矿工程
背景情况:
- 凝材料对于密封空气泄漏和防止地下煤矿中煤炭自燃至关重要.
- 现有的水凝需要在自我愈合,耐火性和在恶劣的采矿条件下的稳定性方面进行增强.
研究的目的:
- 为了合成和表征一种用于采矿应用的新型自我愈合,耐火的水凝.
- 为了研究碳甲基纤维素修饰的两性聚合物水凝的特性和性能.
主要方法:
- 通过接种合成碳甲基纤维素接种的两性共聚合物 (CMC-graft-poly ((AM-co-NaA-co-BAM)).
- 同聚合物与酸 (AlCit) 的离子交联.
- 评估水凝特性,包括粘度,粘性弹性,自我愈合,热稳定性以及防火/灭火能力.
主要成果:
- 在7.5%重量%的CMC含量下,可以达到最佳的增粘性性能.
- 与对照聚合物相比,合成的水凝表现出优越的温度,剪切和盐耐受性.
- 与AlCit交联的水凝表现出良好的粘性弹性,自我愈合,热稳定性和灭火性能.
结论:
- 这种新型的CMC修改的两性聚合物水凝具有出色的自我愈合和消防安全性能.
- 这种材料显示出在地下采矿操作中提高安全性的巨大潜力.
- 双网络结构和可逆的疏水相互作用有助于水凝显著的自我愈合能力.
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