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Updated: Jan 10, 2026

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain

Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain

Published on: March 27, 2018

在高压下对亚酸 (Ba(N₃) ₂) 的分子规模分析:对亚酸离子旋转和相位过渡的同步X射线衍射研究

Xiaoxin Wu¹, Wenhui Jiang¹, Jinwei Zhang¹

¹Key Laboratory of Functional Materials Physics and Chemistry (Ministry of Education), College of Physics, Jilin Normal University, Changchun 130103, China.

Molecules (Basel, Switzerland)

|November 27, 2025

概括

亚酸 (Ba(N₃) ₂) 呈现异构压缩,在高压下经历相变. 亚离子的动态显著影响其结构稳定性,影响其用于合成聚合物的使用.

科学领域:

材料科学材料科学材料科学
固态物理固态物理
无机化学无机化学

背景情况:

亚酸 (Ba(N₃) ₂) 是一种具有潜在应用的双价亚酸.
了解其高压行为对于材料科学和合成至关重要.

研究的目的:

为了研究亚酸的高压行为和相变.
阐明亚离子动态在结构稳定中的作用.

主要方法:

采用同步射线X射线衍射来研究高达28GPa的Ba{N₃) ₂.
在不同压力下分析晶体结构和压缩性.

主要成果:

Ba(N₃) ₂显示出由于亚酸离子排列而导致的异构压缩 (b > a > c).
一个可逆的单临床到单临床阶段过渡发生在2.6GPa.
在11.8GPa.以上观察到潜在的二次过渡.

结论:

酸离子动态是酸的结构稳定性和相位演变的关键.
这些发现对使用亚酸作为聚合物合成的前体有影响.

关键词:

亚酸和酸是什么意思高压机是一种高压机.阶段过渡阶段过渡

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