协同的石膏碳化策略和非接触ITZ量化为CFBFA人工聚合物混凝土
Nuo Xu1, Mingyi Guo1, Yiheng Chen1
1Shanxi Province Key Laboratory of High Efficient & Clean Combustion and Utilization of Circulating Fluidized Bed, Taiyuan University of Technology, 79 Yingze West Street, Taiyuan 030024, China.
Materials (Basel, Switzerland)
|November 27, 2025
概括
这项研究使用石膏和热固化将超过80%的飞灰增强混凝土. 这改善了聚合物和混凝土之间的薄弱接口,提高了机械强度,并使低碳建筑材料成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 土木工程 土木工程是指土木工程.
- 可持续建筑 可持续建筑
背景情况:
- 接口过渡区 (ITZ) 是混凝土的关键弱环,特别是在使用大量的人工聚合物时,例如循环流化床飞灰 (CFBFA).
- 较差的ITZ特性,包括较低的粘合强度和较高的孔隙性,显著限制了基于CFBFA的混凝土的整体机械性能.
研究的目的:
- 研究一种综合战略,将石膏激活和加压烟气热固化 (FHC) 结合起来,以超过80%的基于CFBFA的人工粗聚合物增强混凝土中的ITZ.
- 开发一种用于定量测量ITZ厚度的新方法,并将其与机械性能相关联.
- 阐明负责ITZ改进的微观结构机制.
主要方法:
- 综合处理,包括石膏激活和加压烟气热固化 (FHC).
- 加入超过80%的循环流化床飞灰 (CFBFA) 基人工粗聚合物.
- 开发和应用基于灰度图像的双峰梯度方法,用于非接触ITZ厚度测量.
- 微结构分析 (例如,SEM,XRD) 检查ITZ形态和组成.
主要成果:
- 双重的FHC-石膏处理协同促进了石 (AFt) 的形成和密集的CaCO3的发展,完善了ITZ的微观结构.
- 在ITZ厚度和压力强度之间发现了强烈的反相关性 (R2 = 0.87).
- 微结构改进包括更密集的聚合物内部,增强的矩阵连续性和减少裂连接,从而导致更集成的接口.
- 故障模式从界面主导转向复合控制的行为,表明整体完整性得到了增强.
结论:
- 在量身定制ITZ形态和显著提高基于CFBFA的混凝土的机械完整性方面,FHC-石膏方法非常有效.
- 这一战略通过有效利用工业副产品,为生产高性能,低碳的水泥复合材料提供了可行的途径.
- 开发的ITZ测量技术为这种先进混凝土的质量控制和性能预测提供了宝贵的工具.
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