电子捐赠者-受体相互作用使得共价有机框架的水性合成具有前所未有的结晶性和多孔性,用于从干燥的空气中提取水
Jinglin Gao1, Congcong Yin1, Meng Chen2
1Key Lab of Functional Polymers for Sustainability of Jiangsu, School of Energy and Environment, Southeast University, Nanjing, Jiangsu, P.R. China.
Angewandte Chemie (International ed. in English)
|November 27, 2025
概括
我们开发了一种合成水中的共价有机框架 (COF) 的新方法,克服了结晶性和多孔性的挑战. 这种方法可以实现可持续技术的高质量COF的可扩展生产.
科学领域:
- 材料科学 材料科学 材料科学
- 绿色化学 绿色化学
- 纳米技术纳米技术
背景情况:
- 联有机框架 (COF) 的合成通常需要有机溶剂,这导致了结晶性,多孔性和单体溶解性方面的挑战.
- 现有的方法在可扩展性和实现最佳框架属性方面扎.
研究的目的:
- 开发一种水中合成方法,用于高度结晶和多孔的COF.
- 克服传统COF合成的局限性,包括溶剂使用和动力学挑战.
- 为了实现可扩展的COF生产,以提高可持续应用的性能.
主要方法:
- 在富含电子的催化剂和缺乏电子的单体之间利用电子转移.
- 利用电子供体-接受体 (EDA) 复合形成来提高单体溶解度和反应可逆性.
- 使用水作为反应介质来促进电子转移和降低能量障碍.
主要成果:
- 实现了水中合成具有高度结晶性的COFs,具有多种联系和表面积达到理论极限.
- 证明了EDA介导合成过程的可扩展性.
- 获得的COF具有出色的稳定性和在从干旱的空气中提取水的特殊性能 (0.65gg-1在30%RH).
结论:
- 建立了合成水中高质量的晶体框架的范式,解决了COF合成的长期挑战.
- 以EDA为媒介的方法为先进的COF提供了一个可持续和可扩展的途径.
- 开发的COF显示出在可持续技术,特别是水收集方面的应用潜力很大.
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