通过原子层沉积将多个功能组件集成到活性组合中,以实现高效的转换和CO容忍度
Jiaye Qiu1, Zhongyao Zhang1, Mansheng Liao1
1College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong, 518060, P. R. China.
Small (Weinheim an der Bergstrasse, Germany)
|November 28, 2025
概括
研究人员开发了一种新的WPtRu三金属催化剂 (WPtRu-NC) 用于质子交换膜燃料电池 (PEMFC). 这种催化剂显著增强了氧化反应 (HOR) 活性和CO耐受性,减少了对贵重的依赖.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 催化剂是一种催化剂.
背景情况:
- 质子交换膜燃料电池 (PEMFC) 在氧化反应 (HOR) 中严重依赖 (Pt) 催化剂.
- 原子分散的 Pt 位点提供了对 CO 吸附的一些缓解,但由于微量 CO 中毒而遭受失活.
- 开发高效的低Pt催化剂,提高CO耐受性,对于推进燃料电池技术至关重要.
研究的目的:
- 通过逐步的原子层沉积策略,设计WPtRu三金属组合 (WPtRu-NC).
- 实现原子协同几何学和电子配置的合理设计,以提高HOR性能.
- 建立一个原子精确工程低Pt电催化剂的范式.
主要方法:
- 逐步的原子层沉积以构建WPtRu三金属组合.
- 在PEMFC中进行电化学测试,以评估HOR质量活性和功率密度.
- 射线吸附光谱,现场拉曼光谱,以及理论计算以阐明催化机制.
主要成果:
- 与商业Pt/C相比,WPtRu-NC催化剂的HOR质量活性是商业Pt/C的19倍.
- 在0.6V时达到1.5Wcm-2的高功率密度,具有良好的CO耐受性.
- Pt位点对HOR是活跃的,Ru促进水解离和CO氧化,W提供稳定性.
结论:
- WPtRu-NC催化剂为PEMFC中高效和稳定的HOR提供了一个有希望的低Pt替代品.
- 该研究揭示了能量转换中的三金属集群的通用设计原则.
- 催化剂的原子级工程是开发下一代燃料电池技术的可行策略.
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