谷物边界分离抑制了纳米晶体高合金中的局部短距离排序
Moses A Adaan-Nyiak1, Mack Cleveland2, Benjamin Hewitt1
1Department of Mechanical and Manufacturing Engineering, University of Calgary, 2500 University Drive NW, Calgary, Alberta, T2N 1N4, Canada.
Advanced science (Weinheim, Baden-Wurttemberg, Germany)
|November 30, 2025
概括
在高合金 (HEAs) 中的短距离排序 (SRO) 在纳米晶体 (NC) AlCoCrFeZr合金中被抑制. 纳米结构和颗粒边界分离防止SRO,保持随机固体溶液.
科学领域:
- 材料科学 材料科学 材料科学
- 金工业是金工业的一个方面.
- 纳米技术纳米技术
背景情况:
- 高合金 (HEAs) 具有独特的特性,但倾向于形成短距离排序 (SRO).
- 控制SRO演变对于优化HEA性能至关重要.
- 纳米晶体 (NC) 结构和粒度边界 (GB) 现象可以影响原子的排序.
研究的目的:
- 研究纳米晶体结构和Zr添加对基于AlCoCrFe的HEAs中SRO的影响.
- 了解NC-HEAs中抑制SRO的机制.
- 探索颗粒边界在原子排列中的作用.
主要方法:
- 高级表征:传输电子显微镜 (TEM),高能同步子X射线衍射/对分布函数 (PDF) 和原子探头断层扫描 (APT).
- 计算分析:沃伦-考利系数的计算.
- 合金组成的变化:NC-(AlCoCrFe) 100-xZrx (x = 0-1.5 原子 %).
主要成果:
- 在经过磨砂和 GB 装饰的 NC- ((AlCoCrFe) 100-xZrx 合金中,SRO 被抑制.
- 观察到Cr,Fe和Zr的GB分离,改变了矩阵化学和不利于SRO.
- 计算验证了SRO抑制.
- 尽管GB分离,但矩阵和GB保持了随机固体溶液.
结论:
- 纳米晶体架构和粒度边界分离有效地抑制了AlCoCrFeZr HEAs中的短距离排序.
- 这种抑制机制提供了一种控制原子排列的途径,并保持HEAs中的随机固体溶液.
- 这些发现强调了纳米结构对于定制HEA属性的重要性.
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