在WOx ‐CNT混合膜中稳定n型导电
Ayesha Farooq1,2, Luca Bignardi2,1,2, Matus Stredansky1
1CNR - Istituto Officina dei Materiali (IOM), AREA Science Park, Basovizza, 34149 Trieste, Italy.
概括
研究人员创建了由氧化纳米集群和碳纳米管 (CNT) 的混合膜. 这些薄膜表现出稳定的n型导电性,这是CNT基于纳米结构的兴奋剂的重大进步.
科学领域:
- 材料科学 材料科学 材料科学
- 纳米技术纳米技术
- 化学工程是化学工程的重要组成部分.
背景情况:
- 碳纳米管 (CNT) 通常表现出p型半导体行为.
- 氧化 (WOx) 薄膜通常是p型的.
- 在CNT中实现稳定的n型兴奋剂对于电子应用至关重要.
研究的目的:
- 为了合成WOx纳米集群和CNT的纳米结构混合膜.
- 为了研究这些混合膜的导电行为.
- 探索一种方法,以在CNT中实现空气稳定的n型兴奋剂.
主要方法:
- 使用化学蒸汽沉积和超音速集群束束沉积合成WOx纳米集群和CNTs.
- 制造缺乏氧气的,非静态度的WOx纳米集群.
- 在超高真空中暴露于乙醇下的电阻测量.
主要成果:
- 混合膜显示n型导电,与CNT和WOx的内在p型行为相反.
- 从WOx中空缺的氧气转移到CNT的接口电荷转移被确定为原因.
- 在长时间暴露在空气中后,n型导电保持稳定.
结论:
- 展示了一种新的方法,用于基于CNT的纳米结构的空气稳定型n型兴奋剂.
- 接口电荷传输机制为操纵CNT导电性提供了一条途径.
- 这些发现为使用n型CNT的先进电子设备提供了潜力.
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