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Updated: Jan 6, 2026

The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry
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The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry

Published on: August 25, 2016

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一种基于的甘胺氨酸环氧树脂的合成,加工和性能

Amy Honnig Bassett1, Emre Kinaci1, Giuseppe R Palmese1

  • 1Department of Chemical Engineering, Advanced Materials and Manufacturing Institute (AMMI), Rowan University, 201 Mullica Hill Rd., Glassboro, New Jersey 08028, United States.

ACS omega
|December 1, 2025
PubMed
概括

这项研究合成了 furan diepoxy (FDE) 和其α-chlorohydrin衍生物. 由于增强的交联,α-水素FDE表现出优越的热力学性能,包括更高的储存模量和玻璃过渡温度.

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Amides are synthesized by treating carboxylic acids with amines in the presence of dehydrating agents like dicyclohexylcarbodiimide (DCC).
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Strong bases like NaOH or KOH deprotonate the phthalimide to form the corresponding anion, which acts as a nucleophile. Further, the anion attacks an...
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The Hofmann and Curtius rearrangement reactions can be applied to synthesize primary amines from carboxylic acid derivatives such as amides and acyl azides. In the Hofmann rearrangement, a primary amide undergoes deprotonation in the presence of a base, followed by halogenation to generate an N-haloamide. A second proton abstraction produces a stabilized anionic species, which rearranges to an isocyanate intermediate via an alkyl group migration from the carbonyl carbon to the neighboring...
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Recently, the development of olefin metathesis polymerization advanced the field of polymer synthesis. Simply put, the reorganization of substituents on their double bonds between two olefins in the presence of a catalyst is known as the olefin metathesis reaction. The use of metathesis reaction for polymer synthesis is called olefin metathesis polymerization.
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