Gd-Pt-In In Situ 复合材料具有增强的相对冷却功率和广泛的磁热效应
Aline A de Freitas1, Jessica K P França1, Walajhone O Pereira1
1Center for Sciences of Imperatriz, Federal University of Maranhão (UFMA), Imperatriz, MA 65900-410, Brazil.
ACS omega
|December 1, 2025
概括
一种新的Gd-Pt-In复合材料显示出用于磁性制冷的绝佳潜力. 它的双磁过渡创建了一个广泛的,有效的冷却范围,使其非常适合低温应用.
科学领域:
- 材料科学 材料科学 材料科学
- 凝聚物质物理学 凝聚物质物理学
- 热力学是一种热力学.
背景情况:
- 磁性制冷利用磁热效应 (MCE) 进行高效的冷却.
- 开发具有广泛MCE的材料对于实际的磁性冰箱至关重要.
- 基于加多的化合物以其磁热性质而闻名.
研究的目的:
- 为了合成和表征一种新的Gd-Pt-In复合材料.
- 为了研究Gd-Pt-In复合材料的磁热性质.
- 评估其适用于低温磁制冷的适用性.
主要方法:
- 弧形融合成技术.
- 粉末X射线衍射 (PXRD),扫描电子显微镜 (SEM) 和能量分散X射线光谱 (EDS) 用于结构和组成分析.
- 磁性和特定热量测量以确定磁性转换和磁热参数.
主要成果:
- 该Gd-Pt-In复合物由GdPtIn (76%) 和GdPt (21%) 阶段组成.
- 在67K和63.5K观察到两个连续的铁磁过渡.
- 实现了广泛的磁热效应,最大磁变化 (-ΔSMmax) 为6 J/kg K,相对冷却功率 (RCP) 为368 J/kg,场变化为50 kOe.
结论:
- 由于其连续的磁转换,Gd-Pt-In复合材料表现出显著的磁热性质.
- 其广泛的MCE和高的RCP使其成为低温磁制冷的有希望的材料.
- 这些发现有助于寻找具有多个磁相转换的先进制冷剂材料.
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