基于DO梯度和负载比率分配的新A-OHO工艺,使有毒工业废水中的主流PN/A成为可能
Xiaoqian Cheng1, Acong Chen2, Tuo Wei3
1School of Environment and Energy, South China University of Technology, Guangzhou, Guangdong 510006, China.
Bioresource technology
|December 1, 2025
概括
一种新的废水处理工艺选择性地积累物种,克服了部分化-亚纳摩克斯 (PN/A) 在工业应用中的局限性. 这种优化的A-OHO工艺显著降低了总和能源消耗.
科学领域:
- 环境工程 环境工程
- 废水处理技术 废水处理技术
- 生物反应器设计设计
背景情况:
- 部分化-亚纳摩克斯 (PN/A) 提供节能和碳中和,但面临有毒污染物和比控制的挑战.
- 焦化废水对传统PN/A存在独特的困难,原因是污染物度高和负载变化.
研究的目的:
- 开发和优化一个新的试点规模的焦化废水处理工艺 (A-OHO) 以提高去除.
- 调查溶解氧 (DO) 梯度和DO与污染物比率在物种转化中的关键作用.
- 建立一个实用策略,以普及PN/A在高度工业废水中的应用.
主要方法:
- 实施试点规模的A-OHO工艺,控制溶氧 (DO) 度梯度.
- 利用热力学,动力学和SHAP分析来了解的转化机制.
- 集成机器学习和TCW-ASM3模型用于优化操作条件和模式.
- 发展了A-OHO工艺成为A-OHO配置与并行反应堆 (ONH3和ONO2).
主要成果:
- 通过DO调节,A-OHO工艺成功实现了物种的选择性积累.
- 确定DO度和DO/污染物比率 (DO/COD,DO/NH4+-N) 是关键因素.
- 在A-OHO工艺中,通过控制流量和液压保留时间 (HRT) 来维持无外部碳或再循环的anammox.
- 模拟结果显示,总 (TN) 从148.20 mg/L降至28.56 mg/L,最佳流量比 (0.4) 和HRT (15小时/19小时).
- 与传统方法相比,能源消耗减少到1.55 kWh/m3,节省了3.79 kWh/m3.
结论:
- 开发的A-OHO工艺为克服高度工业废水中PN/A的技术障碍提供了一个可行的策略.
- 这种方法使得有效的总 (TN) 排放控制到非常低的水平.
- 该研究为工业废水管理提供了一个可持续的解决方案,可以节省大量的能源.
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