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Updated: Jan 9, 2026

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
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通过连接模板导向的自组装,选择性地形成金属带

Yoko Sakata1, Ryosuke Nakamura2, Takuho Saito1

  • 1Department of Materials Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan. sakata@chembio.nagoya-u.ac.jp.

Chemical communications (Cambridge, England)
|December 2, 2025
PubMed
概括

这项研究介绍了用于受控自组装的连接模板,选择性地使用柱子[n]和离子形成金属宏循环.

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Metal-Ligand Bonds02:51

Metal-Ligand Bonds

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
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