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在空心碳上的协同Fe-Ni双原子位点,使高性能可充电的空气电池成为可能
Yue Wang1,2, Jianhua Wang3, Xueting Feng1,2
1State Key Laboratory of Flexible Electronics (LoFE), Institute of Advanced Materials (IAM), School of Chemistry and Life Sciences, Nanjing University of Posts & Telecommunications Nanjing China iamyhhan@njupt.edu.cn guanzhenchen123@163.com.
Chemical science
|December 4, 2025
概括
我们在空心碳框架上开发了一种新的铁催化剂,用于可充电的空气电池. 这种催化剂表现出优异的双功能氧气电催化和长期稳定性,提高了电池的性能.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 可充电的空气电池 (ZABs) 需要高效的双功能氧气电催化剂来推进.
- 目前的催化剂往往缺乏实际应用所需的耐用性和活性.
研究的目的:
- 为ZABs开发一种高效且稳定的原子分散Fe-Ni双功能催化剂.
- 为了研究Fe-Ni双站点和空心碳支的协同效应.
主要方法:
- 使用密度差异辅助策略,在空心碳框架 (FeNi-hCN) 上合成原子分散的Fe-Ni催化剂.
- 对氧减少反应 (ORR) 和氧演化反应 (OER) 的电化学性能进行了评估.
- 进行加速降解试验 (ADT) 和长期循环测试以评估稳定性.
- 用密度函数理论 (DFT) 的计算来理解催化机制.
主要成果:
- FeNi-hCN催化剂表现出极好的双功能活性,ORR半波电位为0.91V,OER超电位为330mV,在10mA cm-2.2时表现出极好的双功能活性.
- 催化剂表现出了显著的稳定性,在100,000个ADT循环和240小时的连续OER后保持活性.
- 在水性ZAB中,催化剂达到212 mW cm−2的峰值功率密度和560小时的稳定循环,超过了Pt/C + RuO2.
- DFT的计算证实,Fe-Ni双位降低了*OOH中间体的吸附能量,减少了ORR和OER的能源障碍.
结论:
- 通过密度差异辅助方法合成的FeNi-hCN催化剂,为ZABs提供了卓越的双功能氧电催化活性和稳定性.
- 铁原子和空心碳支之间的协同作用对增强性能至关重要.
- 密度差异辅助策略是一种多功能方法,用于创建各种高性能碳支持催化剂.
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