测量单个胡须的模量
Wenbo Zhai1, Hongsheng Shi1, Wei Liu1
1School of Physical Science and Technology and Shanghai Key Laboratory of High-resolution Electron Microscopy, ShanghaiTech University, Shanghai 201210, China.
概括
测量 (Li) 胡须的机械性能是电池安全的关键. 这项研究发现,带有固体电解质间相 (SEI) 的胡须具有比纯更低的模量,降低了短路风险.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 纳米技术纳米技术
背景情况:
- (Li) 阳极对于先进的电池至关重要,但面临安全挑战.
- 由Li胡须透引起的短路是一个主要的安全问题.
- 胡须的机械性能,特别是固体电解质介相 (SEI) 的机械性能,尚不清楚.
研究的目的:
- 用SEI测量单个电化学沉积Li的Young模量.
- 了解机械性质在Li胡须透和电池安全方面的作用.
- 为了研究对测量的模数有助于的因素.
主要方法:
- 利用现场电场诱导的共振方法.
- 在传输电子显微镜内进行测量.
- 采用原子级成像和模拟用于定量分析.
主要成果:
- 与SEI一起<211>的单个Li胡须的Young模量被测定为3.2 ± 0.2 GPa.
- 这一值低于纯金属的值.
- 一个简单的线性混合模型无法解释减少的扬模量,表明复杂的界面效应.
结论:
- 具有SEI的Li胡须的降低的Young模量表明,由于机械透造成硬短路的可能性较低.
- 复杂的界面微观结构,包括结晶度的变化和与Li2O和有机元件的界面,负责较低的模量.
- 了解这些微结构对于设计更安全的阳极电池至关重要.
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