在fcc-合金中的电荷转移
Paul Roussel1, Sarah C Hernandez2, Sajib K Barman2
1AWE plc, Aldermaston, Reading, Berkshire RG7 4PR, United Kingdom.
概括
合金与改变其电子行为. 射线光电子光谱学和理论计算显示,这些合金中的电荷持续增加.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 核材料 核材料 核材料
背景情况:
- 合金表现出独特的电子特性.
- 了解合金中的电荷转移对于材料开发至关重要.
研究的目的:
- 研究-合金中的电子行为变化.
- 在和之间量化电荷转移.
主要方法:
- 射线光电子光谱 (XPS) 来测量初始状态的奥格尔参数.
- 用Bader的价值电荷分析进行理论计算.
主要成果:
- 实验和理论结果显示出极好的一致性.
- 在稀释的度中观察到大约 -0.6 个对的电荷电子的持续增加.
结论:
- 合金从根本上改变了的电子结构.
- 观察到的电荷转移在研究的合金范围内是不变的,为-相互作用提供了关键的见解.
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