在二维环聚合物中的玻璃动态:大小对刚性多分散性.
Rahul Nayak1,2, Pinaki Chaudhuri1,2, Satyavani Vemparala1,2
1The Institute of Mathematical Sciences, C.I.T. Campus, Taramani, Chennai 600113, India. pinakic@imsc.res.in.
柔软的玻璃材料中的多分散性会根据粒子刚度或大小的变化而不同地影响动力学. 刚度的变化导致有序结构和较慢的动态,而大小的变化会产生不同的群体,影响放松路径.
科学领域:
- 软物质物理学 软物质物理学
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
背景情况:
- 柔软的玻璃材料由可变形的物体组成.
- 了解多分散性对它们动态的影响至关重要.
研究的目的:
- 调查颗粒刚度或大小的多分散性如何影响玻璃动态的出现.
- 模型系统:半柔性环聚合物的二维组件.
主要方法:
- 在固定多分散度 (30%) 的计算模拟.
- 分析环形状,定向顺序和结合放松路径.
- 绘制环形状,顺序和移动性之间的局部相关性.
主要成果:
- 刚性分散导致延长的形状和方向有序的结构,导致动态减速.
- 尺寸分散创造了一个双模态群体 (小圆形,大长长的环),导致挫折和延迟逮捕.
- 观察到明显的动态异质性路径:长寿命域 (刚性) 与透放松 (大小).
结论:
- 多分散性 (度与大小) 的性质决定了软眼镜中的放松途径.
- 度分散导致结构敏感的动态.
- 尺寸分散激活了圆形和延长群体的运动,影响了新出现的玻璃动态.
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