在接触线上的动态囊层相隔离
1Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, PA 15261, USA. qihan.liu@pitt.edu.
Soft matter
|December 5, 2025
概括
一个新的动态膜模型解释了不混合的液体如何在膨胀的固体上引起相位分离. 这种分离,影响湿性质,随着时间的推移增长t^0.32缩放,匹配实验数据.
科学领域:
- 物理化学 物理化学
- 材料科学 材料科学 材料科学
- 流体动力学 流体动力学
背景情况:
- 膨胀的固体在接触不混合的液体时表现出复杂的湿行为.
- 接触线上的表面张力驱动溶剂提取,诱导相位分离.
- 这种现象改变了固体的表面特性,并且依赖于时间.
研究的目的:
- 开发一个动态的度毛细管模型,用于预测膨胀固体的相位分离.
- 为了研究相隔区的依赖时间的演变.
- 量化分离尺寸和时间之间的关系.
主要方法:
- 开发一个动态的毛细管模型.
- 溶剂运输和相位分离动态的数学分析.
- 模型预测与实验观测的比较.
主要成果:
- 该模型预测相隔区大小的时间依赖增加.
- 为了分离增长,得出了时间与0.32 (t^0.32) 的缩放关系.
- 模型预测与现有实验数据有很好的一致性.
结论:
- 动态度毛细管模型准确地捕捉了膨胀的固体上的相分离过程.
- 时间依赖的缩放关系提供了对分离增长的定量理解.
- 这项工作提供了关于胀材料与不混合液体接触时的湿行为的见解.
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