氧硫酸盐的连续脱硫机制通过谷物边界电子转移激活在废弃的化中
Dongyue Hao1, Yanyu Pei1, Jianfei Wang1
1Faculty of Environmental Science and Engineering Institution, Kunming University of Science and Technology, Kunming 650500, China.
Journal of colloid and interface science
|December 9, 2025
概括
本研究介绍了一种可持续的烟气脱硫方法,使用废旧的化石和过氧化硫酸盐 (PMS). 新型异质催化剂实现了100%的二氧化硫去除,与传统系统相比,寿命显著提高.
科学领域:
- 环境科学 环境科学
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
背景情况:
- 从金工艺过程中产生的高二氧化硫 (SO2) 排放带来环境风险.
- 传统的Fe2+/ peroxymonosulfate (PMS) 脱硫系统由于铁消耗而遭受效率下降.
研究的目的:
- 开发一种可持续和高效的异质催化系统,用于使用废物化物的烟气脱硫.
- 克服传统同质Fe2+/PMS系统的局限性.
主要方法:
- 使用废旧的石和PMS开发了一个异质的催化系统.
- 实验条件包括0.1g/L pyrite,0.2M PMS,38-75μm颗粒大小,以及20°C.
- 催化活性,寿命和产生的反应性物种的表征.
主要成果:
- 在长达660分钟的时间内实现了100%的脱硫效率,寿命增加了5.5倍.
- 化石通过硫空隙介导的电子转移促进了Fe (III) /Fe (II) 自循环,从而实现了连续的PMS激活.
- 生成的活性物种包括1O2,SO4•−和Fe(IV)=O,具有1O2主导的非基因通路.
结论:
- 废物化石作为一个可持续的催化剂,用于高效和长期的烟气脱硫.
- 该系统证明了对金固体废物的有效资源利用.
- 提供了一种技术范式,用于协同处理多污染物烟气.
相关概念视频
Electrophilic Aromatic Substitution: Sulfonation of Benzene
7.7K
Sulfonation of benzene is a reaction wherein benzene is treated with fuming sulfuric acid at room temperature to produce benzenesulfonic acid. Fuming sulfuric acid is a mixture of sulfur trioxide and concentrated sulfuric acid.
7.7K
Preparation and Reactions of Sulfides
5.7K
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
5.7K
Sulfur Assimilation
301
Sulfur is an essential element in biological systems, contributing to synthesizing key biomolecules, including amino acids such as cysteine and methionine, and cofactors such as coenzyme A and biotin. Microorganisms primarily assimilate sulfur as sulfate (SO₄²⁻) from the environment, which must undergo a series of biochemical transformations before it can be incorporated into cellular components. As sulfate is highly oxidized, it must undergo assimilatory sulfate reduction to...
301
The Sulfur Cycle
51.6K
Sulfur, an important element in the chemical makeup of proteins, is recycled through the atmosphere and aquatic and terrestrial environments. Found in the atmosphere as sulfur dioxide (SO2), sulfur is released by decaying organisms, weathered rocks, geothermal vents, volcanos, and burning fossil fuels. It is deposited into the ecosystem, cycled through the biotic community, and either released back into the atmosphere as gas or deposited in marine sediment for long-term storage and eventual...
51.6K
Anoxygenic Photosynthesis
1.1K
Anoxygenic photosynthesis is a phototrophic process that captures light energy to drive carbon fixation without producing molecular oxygen. Unlike oxygenic photosynthesis, which utilizes water as an electron donor and releases oxygen, anoxygenic phototrophs use alternative electron donors such as hydrogen sulfide (H₂S), elemental sulfur (S⁰), or thiosulfate (S₂O₃²⁻). This process is carried out by diverse groups of bacteria, including purple bacteria, green...
1.1K
Pyruvate Oxidation
168.1K
After glycolysis, the charged pyruvate molecules enter the mitochondria via active transport and undergo three enzymatic reactions. These reactions ensure that pyruvate can enter the next metabolic pathway so that energy stored in the pyruvate molecules can be harnessed by the cells.
First, the enzyme pyruvate dehydrogenase removes the carboxyl group from pyruvate and releases it as carbon dioxide. The stripped molecule is then oxidized and releases electrons, which are then picked up by NAD+...
First, the enzyme pyruvate dehydrogenase removes the carboxyl group from pyruvate and releases it as carbon dioxide. The stripped molecule is then oxidized and releases electrons, which are then picked up by NAD+...
168.1K


