在Nd-CoOx的呼吸模式中,用于活跃和稳定的质子交换膜水电解
Yong Feng1, Jianhua Wang2, Kun Feng3
1Institute of Functional Nano and Soft Materials Laboratory (FUNSOM), Jiangsu Key Laboratory of Advanced Negative Carbon Technologies, Soochow University, Suzhou, China.
Nature communications
|December 9, 2025
概括
一个新的低成本的氧化物催化剂与新插入 (Nd-CoOx) 显著改善酸性水电解的绿色生产. 这种持久的催化剂提供了高效率和稳定性,为可持续的经济铺平了道路.
科学领域:
- 电化学 电化学 电化学
- 材料科学 材料科学 材料科学
- 绿色化学 绿色化学
背景情况:
- 质子交换膜水电解对于绿色经济至关重要.
- 目前依赖昂贵的贵金属催化剂阻碍了广泛采用.
- 需要具有成本效益和高效的电催化剂,用于酸氧演化反应 (OER).
研究的目的:
- 开发一种低成本,高性能的催化剂,用于酸水电解.
- 调查氧气空缺和新插入在氧化物催化剂中的作用.
- 为了提高氧气演化反应催化剂的效率和长期稳定性.
主要方法:
- 合成一个氧化物催化剂与氧空缺和Nd-插入 (Nd-CoOx).
- 催化剂在酸性OER中的性能的电化学表征.
- 在现场进行X射线吸收光谱和拉曼光谱,以阐明催化机制和稳定性.
主要成果:
- 对于酸性OER,Nd-CoOx催化剂在10 mA cm-2时达到317 mV的低超电位.
- 证明了显著的稳定性,在800多小时内保持性能.
- 在水电解中,Nd-CoOx表现出很好的性能,在1.69V的电压下达到200mA cm-2的低降解.
结论:
- 在Co3O4中氧气空缺和Nd插入显著提高了催化活性和稳定性.
- 在OER期间,Nd通过灵活的"呼吸模式"来促进长期稳定.
- 开发的Nd-CoOx催化剂为绿色生产提供了一个有希望的,具有成本效益的替代方案.
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