循环金属中的不同长度的二氨酸桥 (Diphosphine Bridge) ((II) 通过调节轨道重叠来调节光物理学的度

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Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
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Sarah Kromer1, Xinzheng Yang2, Reem Alameh1

  • 1Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, United States.

Inorganic chemistry
|December 10, 2025
PubMed
概括

中的三酸连接物 (tridentate ligands) 在二极管中增强金属-金属-连接物电荷转移 (MMLCT) 光物理. 较短的Pt-Pt距离和更大的轨道重叠导致红移MMLCT特征和更快的兴奋状态人口.

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