在Na0.5Bi0.5TiO3基铁电器中介电异常的性质
Eriks Birks1, Marija Dunce1, Šarūnas Svirskas2
1Institute of Solid State Physics, University of Latvia, Kengaraga 8, LV-1063 Riga, Latvia.
Materials (Basel, Switzerland)
|December 11, 2025
概括
在 bismuth titanate (Na0.5Bi0.5TiO3) 中的介电电容率表现出不寻常的行为. 一种新的解释将此归因于非铁电相之间的相位过渡,与放松或铁电模型保持一致.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 介电材料 介电材料
背景情况:
- 基于甲酸盐 (Na0.5Bi0.5TiO3) 的材料表现出复杂的介电性电容性取决于温度和频率.
- 这种行为与经典的铁电和传统的放松铁电有所不同,这带来了与结构相位过渡相关的解释挑战.
研究的目的:
- 提出对Na0.5Bi0.5TiO3 (NBT) 基材料的介电性行为的新解释.
- 为了比较分析非极化和极化NBT和NBT-CaTiO3固体溶液中的温度频率电容性数据.
主要方法:
- 在广泛的频率范围 (10 Hz-100 MHz) 上研究过电电容量.
- 在非极化和极化NBT和0.95Na0.5Bi0.5TiO3-0.05CaTiO3样本中分析了温度频率依赖.
主要成果:
- 观察到一个分散的,独立于频率的电容度最大值,其肩部依赖于频率.
- 确定了由于两个非铁电相之间的相变而导致的的电容变化和热歇斯底里.
- 证明排除这种过渡会显示出与经典放松型铁电相一致的行为.
结论:
- 基于NBT的材料中异常的介电反应是由非铁电相之间的相变解释的.
- "呼吸"模型提供了一个统一的框架,用于理解NBT的放松剂类特征,当这种过渡被考虑时.
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