预测聚合物的非线性粘弹性-粘弹性行为的实验和分析框架
Alen Oseli1, Matic Šobak1, Lidija Slemenik Perše1
1Laboratory of Experimental Mechanics, Faculty for Mechanical Engineering, University of Ljubljana, Aškerčeva ulica 6, 1000 Ljubljana, Slovenia.
Polymers
|December 11, 2025
概括
这项研究引入了一种先进的聚合物模型,可以准确预测粘弹性-粘可塑性行为,捕获材料流和不可恢复的过程,用于增强材料响应分析.
科学领域:
- 聚合物科学 聚合物科学
- 材料科学 材料科学 材料科学
- 类风病学 类风病学 类风病学
背景情况:
- 沙佩里的非线性粘弹性模型是聚合物行为分析的基础.
- 了解结合粘弹性和粘可塑性反应对于聚合物应用至关重要.
- 现有的模型可能无法完全捕捉聚合物中不可逆转的变形过程.
研究的目的:
- 扩展沙佩里模型,将粘性可塑性和材料流量纳入其中.
- 开发一个参数识别和多尺度分析的框架.
- 为了准确预测不同负载条件下的聚合物行为.
主要方法:
- 沙佩里非线性粘弹性模型的理论扩展.
- 纳入与结构和负载相关的不可恢复的过程.
- 评估粘弹性和粘塑性贡献的多尺度分析.
- 在无形ABS和半晶POM上进行了回收试验.
主要成果:
- 扩展模型准确地预测了不到5%的误差的聚合物行为.
- 在模型预测和实验数据之间观察到异常一致.
- 甚至在线性粘弹性域内也检测到了粘弹性菌株.
结论:
- 开发的模型有效地捕捉了现实的聚合物反应,包括不可回收的菌株.
- 该模型提供了对材料流和粘性可塑性的洞察,与产量现象不同.
- 这种预测工具可以适应各种聚合物系统和应用.
相关概念视频
Members Made of Elastoplastic Material
347
The behavior of elastoplastic materials under bending stresses, particularly in structural members with rectangular cross-sections, is crucial for predicting material responses and understanding failure modes. Initially, when a bending moment is applied, the stress distribution across the section follows Hooke's Law and is linear and elastic. This distribution means the stress increases from the neutral axis to the maximum at the outer fibers, up to the elastic limit.
As the bending moment...
As the bending moment...
347
Plastic Behavior
497
A material's elastic behavior is characterized by the disappearance of stress once the load is removed, allowing the material to return to its original state. However, when stress surpasses the yield point, yielding commences, marking the onset of plastic deformation or permanent set. This change from elastic to plastic behavior is influenced by the peak stress value and the duration before the load is removed. An intriguing observation occurs when a specimen is loaded, unloaded, and...
497
Residual Stresses in Bending
495
In the study of elastoplastic members subjected to bending moments, understanding the loading and unloading phases is crucial for assessing material behavior and structural integrity. During the loading phase, as the bending moment increases, the material initially responds elastically, adhering to Hooke's Law, where stress is directly proportional to strain. When the load exceeds the yield strength, plastic deformation occurs, resulting in permanent strain and deformation that remains even...
495
Relation between Poisson's ratio, Modulus of Elasticity and Modulus of Rigidity
523
Deformation occurs in axial and transverse directions when an axial load is applied to a slender bar. This deformation impacts the cubic element within the bar, transforming it into either a rectangular parallelepiped or a rhombus, contingent on its orientation. This transformation process induces shearing strain. Axial loading elicits both shearing and normal strains. Applying an axial load instigates equal normal and shearing stresses on elements oriented at a 45° angle to the load axis.
523
Hooke's Law
1.4K
Hooke's law, a pivotal principle in material science, establishes that the strain a material undergoes is directly proportional to the applied stress, defined by a factor called the modulus of elasticity or Young's modulus.
1.4K
Types of Step-Growth Polymers: Polyesters
2.5K
The introduction of polyesters has brought major development to the textile industry. The wrinkle-free behavior of polyester blends has eliminated the need for starching and ironing clothes.
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the polymer...
Polyesters are commonly prepared from terephthalic acid and ethylene glycol; the crude product is known as poly(ethylene terephthalate) or PET. However, polyesters are synthesized industrially by transesterification of dimethyl terephthalate with ethylene glycol at 150 °C. The two reactants and the polymer...
2.5K


