通过废弃生物质的部分脱氧化获得的生物炭的合成和表征
Gabriel Vasilievici1, Mia Sanda2, Marian Băjan2
1National Institute for Research Development for Chemistry and Petrochemistry-ICECHIM-București, 202 Spl. Independenței, 060021 Bucharest, Romania.
Molecules (Basel, Switzerland)
|December 11, 2025
概括
在热处理前减少葡萄种子中的素,可以提高生物炭的产量. 这种新的方法提高了孔积,并保持了多烯吸附能力,为生物质衍生吸附剂提供了更有效的激活过程.
科学领域:
- 材料科学 材料科学 材料科学
- 化学工程是化学工程的重要组成部分.
- 环境科学 环境科学
背景情况:
- 生物炭激活通常涉及高温蒸汽处理以去除阻塞孔的焦油.
- 这个过程耗费大量能量,需要长时间的时间.
- 需要替代方法来有效地激活生物碳.
研究的目的:
- 调查葡萄种子初步脱氧对生物炭性质的影响.
- 为了评估从预处理的葡萄种子中生产的生物炭的多烯吸附能力.
- 探索生物炭的低温激活方法.
主要方法:
- 葡萄种子用硫化处理,以减少红素含量.
- 预处理的生物质用酸或化进行调节,然后干燥和烧焦.
- 合成的生物炭吸附剂使用SEM,FTIR,XRD和纹理分析进行了表征.
- 在连续固定床系统中评估了烯吸附能力.
主要成果:
- 酸或化调节使生物炭的特定表面积增加了20%以上,酸产生了更大的增加.
- 用ZnCl2预处理的生物炭显示二烯吸附能力为0.11cm3/g.
- 用酸预处理的生物炭具有0.14cm3/g的多烯吸附能力.
- 预先的脱保持了与其他吸附剂在较低激活温度下可比的托洛吸附能力.
结论:
- 在热处理前在葡萄种子中部分溶解红素是生物炭激活的可行策略.
- 这种方法提高了特定的表面积,并保持了显著的多烯吸附能力.
- 这些发现表明,生产高性能生物炭吸附剂的更高能效途径.
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