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Updated: Jan 9, 2026

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电荷分布中的等离子增强不对称性解释了Pd-Tipped Au Nanorod的酸增加的H2生产率

Leonardo Biancorosso1, Emanuele Coccia1

  • 1Dipartimento di Scienze Chimiche e Farmaceutiche, University of Trieste, via L. Giorgieri 1, 34127, Trieste, Italy.

The journal of physical chemistry letters
|December 11, 2025
PubMed
概括

等离子纳米结构可以提高气生产效率. 模拟显示,金纳米棒中的等离子体共振增强了电子转移到反应中间体,从而从酸中产生更多的气.

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π Electron Effects on Chemical Shift: Overview01:27

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An applied magnetic field causes loosely bound π-electrons in organic molecules to circulate, producing a local or induced diamagnetic field over a large spatial volume. As the molecules tumble in solution, the field generated by π-electrons in spherical substituents results in a zero net field. However, the net field generated by π-electrons in non-spherical substituents is not zero. The effect of this induced field depends on the orientation of the molecule with respect to B0,...
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