阴离子/离子对干扰策略:提高场衍生的碳阳极的Na-存储性能
Jiale Zhao1, Xuyang Jian1, Ning Sun1,2
1State Key Laboratory of Organic-Inorganic Composites, Beijing Key Laboratory of Electrochemical Process and Technology for Materials, Beijing University of Chemical Technology, Beijing 100029, China.
ACS applied materials & interfaces
|December 12, 2025
概括
研究人员使用酸将软碳转化为硬碳,大大提高了离子储存能力. 这一进步为开发用于离子电池的高效碳阳极提供了有希望的途径.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 是一种丰富的,具有成本效益的碳前体.
- 来自的软碳由于其石墨结构和狭窄的层间间距,对离子 (Na-ion) 储存有局限性.
- 开发高效的碳阳极对于实际的离子电池至关重要.
研究的目的:
- 为了设计具有增强的Na-离子储存性能的取碳.
- 用一种新的共干扰方法将软碳转化为硬碳.
- 研究微晶体秩序和孔隙结构对离子存储的协同效应.
主要方法:
- 使用乙酸盐的阴离子/离子协干扰方法被采用.
- 从软碳转变为硬碳的控制转化已经实现.
- 进行了改性碳结构的表征,包括微晶秩序和孔隙结构.
主要成果:
- 经过修改的取碳 (最佳样本) 显示出丰富的闭孔和增加的伪图形相位.
- 离子存储容量从87.7mAhg-1显著提高到262.6mAhg-1.
- 首次达到86.5%的库伦比克效率.
- 一个Na-ion全电池的可逆容量为339.8 mAh g-1和能量密度为263.1 Wh kg-1.
结论:
- 阴离子/离子共干扰方法有效地将衍生的碳转化为Na-离子电池的高性能阳极材料.
- 微晶结构和闭孔之间的协同作用是增强离子储存的关键.
- 这项工作提出了一个新的策略,用于设计高效的碳阳极,用于实际的离子电池应用.
相关概念视频
Formation of Complex Ions
25.6K
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
25.6K
Ionic Strength: Effects on Chemical Equilibria
2.5K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
In this solution, the primary...
2.5K
Ion Exchange
1.1K
Ion exchange chromatography separates charged molecules from a solution by reversibly exchanging them with mobile, or 'active', ions associated with the oppositely charged stationary phase. This method can be used to separate ions, soften and deionize water, and purify solutions. The polymers comprising the ion-exchange column are high-molecular-weight and chemically stable polymers, crosslinked to be porous and essentially insoluble. They are also functionalized with either acidic or...
1.1K
Ionic Bonding and Electron Transfer
48.5K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
48.5K
Ionic Bonds
127.3K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
127.3K
Qualitative Analysis
23.6K
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a series of selective precipitations with different chemical reagents, each reaction producing a characteristic precipitate for a specific group of cations. Metal ions within a group are further separated by varying the pH, heating the mixture to redissolve a precipitate, or adding other reagents to form complex ions.
For instance, group IV...
For instance, group IV...
23.6K


