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在可结晶弹性体中突然断裂过渡的机制
Zehao Fan1, Fengjia Liu1, Shi-Qing Wang1
1School of Polymer Science and Polymer Engineering, University of Akron, Akron, Ohio, 44325, USA. swang@uakron.edu.
Soft matter
|December 12, 2025
概括
这项研究揭示了在持续拉伸下,化天然 (NR) 中发生的五种突变. 这些与温度,拉伸率和隙大小相关的过渡取决于应变诱导结晶 (SIC),与网络崩相竞争.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物物理 聚合物物理
- 材料机械学 材料机械学
背景情况:
- 化天然 (NR) 在拉伸应力下表现出复杂的破裂和断裂行为.
- 了解这些转变对于预测材料性能和故障模式至关重要.
研究的目的:
- 理论分析和实验研究在连续拉伸的NR中断裂和断裂过渡.
- 解释这些过渡的突然性质基于一种键解离的动力学理论 (KTBD).
主要方法:
- 使用键解离的动力学理论 (KTBD) 的理论分析.
- 实验研究涉及在不同条件下 (温度,拉伸率,口大小) 持续拉伸火山化天然.
主要成果:
- 证实了以前报告的破裂过渡在没有隙的NR与温度.
- 预测并证实了在没有隙的NR中出现新的破裂过渡,在高温下具有拉伸率.
- 在预约NR中观察到两个额外的骨折过渡,拉伸速率和温度的变化.
- 使用KTBD解释了使用KTBD观察到的五种转变的突然性质,将它们与应变诱导结晶 (SIC) 联系起来.
结论:
- 确定并解释了NR破裂和骨折中的五个突变过渡.
- 这些转变是由应变诱导结晶 (SIC) 和通过链分裂的网络破裂之间的竞争决定的.
- 材料时间尺度 (网络寿命,SIC时间尺度,实验时间尺度) 之间的相互作用决定了这些过渡.
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