使用双金属浸活性炭从水溶液中去除四环环素,这种活性炭是通过一阶段干热解法合成的,这种合成是用棘核的干热解法进行的
Hakimeh Sharififard1, Behniya Hafezi2
1Chemical Engineering Department, Yasouj University, Yasouj, Iran. hakimeh.sharifi@gmail.com.
Scientific reports
|December 12, 2025
概括
一种新的铁活性碳复合物有效地从水中去除四环素. 这种吸附剂显示出高容量和稳定性,为制药污染物清除提供了有希望的解决方案.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
- 吸附科学 吸附科学
背景情况:
- 制药污染物,如四环素 (TC),对水生生态系统构成重大威胁.
- 从废水中有效地去除TC对于环境保护至关重要.
研究的目的:
- 为了合成和描述一种新的双金属Fe-Mn浸活性碳 (Fe:Mn:AC) 复合材料.
- 为了研究Fe:Mn:AC从水溶液中去除四环素的效率.
- 为了阐明吸附机制和动力学.
主要方法:
- 一步干热解合成Fe:Mn:AC复合物.
- 批量吸附实验研究pH,时间和初始度的影响.
- 吸附动力学和异热模拟 (埃洛维奇,兰格穆尔).
- 使用各种技术对吸附剂进行表征.
主要成果:
- 铁::AC表现出具有丰富的功能组的中孔结构.
- 最佳的TC去除发生在pH 6.
- 吸附遵循埃洛维奇动力学和兰格穆尔异热模型.
- 在25°C时最大吸附能力达到463.040 mg/g.
- 吸附机制包括结,M-π复合,易斯酸,π-π相互作用和孔隙填充.
结论:
- 该Fe:Mn:AC复合物是一种高效的吸附剂,用于去除四环素.
- 吸附剂在五个周期内表现出良好的稳定性和可重复使用性.
- 这种材料显示出在处理药物污染水中的实际应用潜力.
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