破裂能力-稳定性贸易-Off 在层氧化物通过透介导双位工程通过透介导双位工程
Minli Luo1, Zi-Ao Jin1, Xiaohong Liu1
1State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing, China.
ChemSusChem
|December 14, 2025
概括
这项研究引入了一种新的双站点修改,用于离子电池 (SIB) 中的高氧化物阴极. 优化的材料实现了高容量和出色的循环稳定性,推进了SIB技术.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 储能 储能 储能 储能 储能 储能
背景情况:
- 由于的丰富性,分层高氧化物对离子电池 (SIB) 是有前途的.
- 传统的设计面临着结构完整性和容量之间的权衡.
- 需要一种新的方法来提高SIB阴极性能.
研究的目的:
- 为SIBs开发一个先进的高氧化物阴极.
- 为了提高特定容量和长期循环稳定性.
- 为了研究双站点修改的结构和电化学好处.
主要方法:
- 合成了一个O3型Na0.91Ca0.02(Ni0.3Li0.05Fe0.1Mn0.4Ti0.1Mg0.05) O2阴极.
- 应用的双站点修改:Ca2+柱和高过渡金属板.
- 进行了电化学测试 (容量,速率,循环) 和现场X射线衍射.
主要成果:
- 实现了高可逆容量 (145.2mAhg-1在0.1°C).
- 证明了显著的速率能力 (81.3%在2C保持) 和循环稳定性 (92.6%在800个循环后在5C).
- 抑制了有害的P3-OP2相位过渡,并增强了Na+运输.
结论:
- 协同工程和阴离子替代使高容量与可循环性相协调.
- 双站点修改策略为实用的高能SIB阴极提供了一条途径.
- 这项工作推进了下一代离子电池材料的设计原则.
相关概念视频
Ionic Strength: Effects on Chemical Equilibria
2.5K
The addition of an inert ionic compound increases the solubility of a sparingly soluble salt. For example, adding potassium nitrate to a saturated solution of calcium sulfate significantly enhances the solubility of calcium sulfate. Le Châtelier's principle cannot predict this shift in the equilibrium. Instead, this could be explained in terms of changes in the effective concentration of the ions in solution in the presence of added inert salt.
In this solution, the primary...
In this solution, the primary...
2.5K
Trends in Lattice Energy: Ion Size and Charge
26.4K
An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
26.4K
MOS Capacitor
1.4K
A Metal-Oxide-Semiconductor (MOS) capacitor is a fundamental structure used extensively in semiconductor device technology, particularly in the fabrication of integrated circuits and MOSFETs (metal-oxide-semiconductor field-effect transistors). The MOS capacitor consists of three layers: a metal gate, a dielectric oxide, and a semiconductor substrate.
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
1.4K
Ionic Bonding and Electron Transfer
48.5K
Ions are atoms or molecules bearing an electrical charge. A cation (a positive ion) forms when a neutral atom loses one or more electrons from its valence shell, and an anion (a negative ion) forms when a neutral atom gains one or more electrons in its valence shell. Compounds composed of ions are called ionic compounds (or salts), and their constituent ions are held together by ionic bonds: electrostatic forces of attraction between oppositely charged cations and anions.
48.5K
Ionic Crystal Structures
16.7K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
16.7K
The Born-Haber Cycle
25.0K
Lattice Energy
25.0K


