强大的水下环氧粘合剂通过动态共价键介导的双阶段固化实现了强大的水下环氧粘合剂
Zhipeng Liu1, Ying Tang1, Jiadong Yang2
1School of Chemical Engineering and Technology, Guangdong Engineering Technology Research Center for Platform Chemicals from Marine Biomass and their Functionalization, Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai), Sun Yat-sen University, Zhuhai 519082, China.
ACS macro letters
|December 16, 2025
概括
这项研究引入了一种新的两阶段固化方法,用于使用聚硫酸的水下强环氧粘合剂. 该创新策略实现了高水下结合强度,并使先进材料应用的绿色可回收性成为可能.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
背景情况:
- 由于水界干扰,开发强大的水下粘合剂具有挑战性.
- 现有的环氧粘合剂往往缺乏高效的水下粘合能力和可回收性.
研究的目的:
- 为坚固的水下环氧粘合剂提出一个创新的两阶段固化策略.
- 合成一种基于多酸的新型环氧固化剂.
- 为了实现高水下结合强度和绿色可回收性.
主要方法:
- 通过使用动态醇-二硫化物交换的无溶剂环开聚合合成的聚 ((thioctic酸).
- 采用了两阶段的固化过程:第一阶段的点击反应 (thiol-epoxy) 和第二阶段的 carboxyl-epoxy反应.
- 利用硫酸的适应性分子架构用于水排放和界面相互作用.
主要成果:
- 实现了高达 16.4 MPa 的水下显著粘合强度.
- 开发出耐水长链聚合物,有效地驱逐接口水.
- 证明了绿色可回收性,允许重复拆卸粘合剂.
结论:
- 拟议的两阶段固化策略有效地创造了强大的水下环氧粘合剂.
- 聚乙烯 (聚乙烯) 作为实现高性能和可回收性的关键组成部分.
- 这种方法为需要耐用性和可持续性的水下粘合应用提供了有希望的解决方案.
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