氧气辅助的B-N编码能够为n型钻石提供浅层BN2捐赠者
Dongliang Zhang1,2, Xiang Sun3,4, Wei Shen1,3,4
1School of Integrated Circuits, Wuhan University, Wuhan 430072, China.
Research (Washington, D.C.)
|December 17, 2025
概括
现在可以使用氧辅助-配合 (BN2) 实现稳定的n型钻石导电性. 这种方法创造了浅层的捐赠体,使得复制性电子运输能够用于先进的钻石电子.
科学领域:
- 材料科学 材料科学 材料科学
- 固态物理 固态物理
- 半导体研究 半导体研究
背景情况:
- 钻石中稳定的n型导电性是一个长期存在的挑战,因为它具有深度的供体水平和多补偿.
- 传统的兴奋剂方法未能在钻石中实现可靠的n型行为.
研究的目的:
- 开发一种方法,在钻石中实现稳定的n型导电性.
- 为了研究氧气辅助-配合 (BN2) 在钻石中创造浅层捐赠者的潜力.
主要方法:
- 微波等离子体化学蒸气沉积 (MPCVD) 与氧气辅助的B-N编码.
- 第一个原则计算,以识别和描述BN2捐赠体复合体.
- 试验优化BN2 codoping的生长窗口.
主要成果:
- 确定了BN2作为一个浅层的,耐应变的供体,被氧气稳定,抑制更深层的缺陷.
- 实现了可重复的电子导电,度>10^19 cm^-3和流动性为4.05 cm^2/(V·s).
- 证明了以钻石为基础的pN连接与p型2H-MoTe2表现出纠正行为.
结论:
- 氧气辅助B-N编码是实现n型钻石的可行策略.
- BN2捐赠体的浅激活能量 (~21.1 meV) 促进了有效的n型传输.
- 接口质量对于未来的钻石电子设备至关重要,为高性能应用铺平了道路.
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