臭氧的干沉积到淡水湖面的表面
Audrey E Lyp1, Rebecca Z Fenselau1, Delaney B Kilgour1
1Department of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, United States.
概括
臭氧干沉积到淡水湖是显著的,由溶解有机碳 (DOC) 驱动. 这个过程会影响臭氧的产生,特别是在浅水边界层.
科学领域:
- 环境化学环境化学
- 大气科学 大气科学
- 临界技术 临界技术
背景情况:
- 热带层的臭氧 (O3) 损失主要是由于与和海水中的溶解有机碳 (DOC) 的反应.
- 臭氧干沉积到淡水湖的研究不足,空气质量模型缺乏实验数据.
研究的目的:
- 用淡水湖泊样本量化臭氧 (O3) 反应性的测量.
- 了解溶解有机碳 (DOC) 在O3沉积到内陆水中的作用.
- 通过提供O3沉积率数据来改善区域空气质量模型.
主要方法:
- 从威斯康星州和密歇根州的淡水湖收集了水样.
- 用这些湖水样本测量了臭氧 (O3) 的反应性.
- 分析了O3反应性和DOC度之间的关系.
主要成果:
- 湖水中的臭氧 (O3) 反应性与海水中的反应性相当.
- 臭氧沉积率可以根据湖水DOC度进行参数化.
- 干沉积到淡水湖中显著减少了臭氧净产量.
结论:
- 溶解有机碳 (DOC) 是控制臭氧 (O3) 沉积到淡水湖中的关键因素.
- 臭氧干沉积到内陆水域是一个重要的大气过程.
- 对O3沉积的准确参数化对于区域空气质量建模至关重要.
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