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相关概念视频

Nuclear Transmutation03:20

Nuclear Transmutation

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Nuclear transmutation is the conversion of one nuclide into another. It can occur by the radioactive decay of a nucleus, or the reaction of a nucleus with another particle. The first manmade nucleus was produced in Ernest Rutherford’s laboratory in 1919 by a transmutation reaction, the bombardment of one type of nuclei with other nuclei or with neutrons. Rutherford bombarded nitrogen-14 atoms with high-speed α particles from a natural radioactive isotope of radium and observed...
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Valence Bond Theory02:42

Valence Bond Theory

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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
11.1K
Nuclear Stability03:18

Nuclear Stability

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Protons and neutrons, collectively called nucleons, are packed together tightly in a nucleus. With a radius of about 10−15 meters, a nucleus is quite small compared to the radius of the entire atom, which is about 10−10 meters. Nuclei are extremely dense compared to bulk matter, averaging 1.8 × 1014 grams per cubic centimeter. If the earth’s density were equal to the average nuclear density, the earth’s radius would be only about 200 meters.
To hold positively charged protons together...
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Radioactivity and Nuclear Equations03:18

Radioactivity and Nuclear Equations

26.8K
Nuclear chemistry is the study of reactions that involve changes in nuclear structure. The nucleus of an atom is composed of protons and, except for hydrogen, neutrons. The number of protons in the nucleus is called the atomic number (Z) of the element, and the sum of the number of protons and the number of neutrons is the mass number (A). Atoms with the same atomic number but different mass numbers are isotopes of the same element.
A nuclide of an element has a specific number of protons and...
26.8K
Electron Configuration of Multielectron Atoms03:26

Electron Configuration of Multielectron Atoms

64.0K
The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
64.0K
Nuclear Binding Energy02:13

Nuclear Binding Energy

14.6K
The difference between the calculated and experimentally measured masses is known as the mass defect of the atom. In the case of helium-4, the mass defect indicates a “loss” in mass of 4.0331 amu – 4.0026 amu = 0.0305 amu. The loss in mass accompanying the formation of an atom from protons, neutrons, and electrons is due to the conversion of that mass into energy that is evolved as the atom forms. The nuclear binding energy is the energy produced when the atoms’ nucleons are bound...
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相关实验视频

Updated: Jan 8, 2026

Preparing an Isotopically Pure 229Th Ion Beam for Studies of 229mTh
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Preparing an Isotopically Pure 229Th Ion Beam for Studies of 229mTh

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一个具有Th-O-Th单位的双核复合体.

Yifei He1,2, Yichen Huang3, Kang Liu4

  • 1State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University Yinchuan 750021 China xiangyuliu432@126.com gy202054@163.com.

RSC advances
|December 18, 2025
PubMed
概括
此摘要是机器生成的。

研究人员用桥合成了一种双核复合体. 密度函数理论的计算揭示了-氧-键的显著共价性,表明强烈的共价相互作用.

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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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科学领域:

  • 有机金属化学 有机金属化学
  • 无机化学 无机化学
  • 材料科学 材料科学 材料科学

背景情况:

  • 复合物由于其独特的电子特性和潜在的应用而引起人们的兴趣.
  • 了解氧系统中的结合是预测反应性和稳定性的关键.
  • 特拉联体为金属离子提供了一个强大的协调环境.

研究的目的:

  • 为了合成和表征一种新的双核复合体与桥.
  • 为了研究Th-O-Th单元的电子结构和粘合特性.
  • 为了比较Th-O键与Th-N键的共价性质.

主要方法:

  • 使用特拉联体和化合成复合物.
  • 用KC8进行减少处理,以形成oxobridged二度体.
  • 双核复合体的结构确定X射线晶体学.
  • 密度函数理论 (DFT) 计算来分析粘合.

主要成果:

  • 从化前体中形成了一个二度复合物[TMS].
  • 用KC8进行的治疗产生了双核氧桥式复合物[TMS Th) ].
  • 晶体结构显示了一个对称的Th-O-Th单元,其Th-O键的长度为2.271(2) Å.
  • DFT计算表明Th-O-Th相互作用具有显著的共价性.

结论:

  • 合成为双核复合体提供了一条新的途径.
  • Th-O-Th 键表现出相当大的共价性质,超过了类似的 Th-N-Th 系统.
  • 这些发现有助于理解氧化合物中的结合及其电子特性.