微量甲烯表面改性Na2CO3用于通过改变产品层结构来增强低温干燥SO2的捕获
Huan Wang1, Longyuan Lin2, Zhongkai Zhao3
1School of Environment and Resource, Southwest University of Science and Technology, Mianyang 621010, China; School of Mechanical Engineering, Sichuan University of Science and Engineering, Zigong 643000, China.
Journal of hazardous materials
|December 18, 2025
概括
使用甲烯的新型表面修饰显著提高碳酸的碳酸盐.
科学领域:
- 环境化学环境化学
- 材料科学 材料科学 材料科学
背景情况:
- 有效控制二氧化硫 (SO2) 排放对空气质量至关重要.
- 非可再生的干式烟气脱硫适用于特定的工业应用.
- 碳酸 (Na2CO3) 具有较高的SO2理论容量,但反应性和被动性较低.
研究的目的:
- 为了增强二氧化的吸收和碳酸的吸附剂利用.
- 开发一种实用且低能耗的Na2CO3.3表面修饰方法.
- 调查 SO2 捕获性能增强背后的机制.
主要方法:
- 表面修改了Na2CO3的表面,其中含有微量甲.
- 在各种条件下测试SO2吸收和吸附剂利用率.
- 结构和组成的表征 (例如,SEM,XRD) 和机械分析.
主要成果:
- olphthalein的修改使SO2的吸收增加了约530%,吸附剂的利用率从9.8%增加到62.5%.
- 优化改性吸附剂 (PP-Na2CO3) 在130-150°C和7.9-14.7%体积的水蒸气下表现出卓越的性能.
- 增强的SO2吸收是二碳酸 (NaHCO3) 的1.84倍.
结论:
- olphthalein的修改克服了低温干燥烟气处理的Na2CO3限制.
- 由甲素形成的功能性活性接口增强了SO2和H2O吸附.
- 修改后的产品层形态减轻了孔隙堵塞,提高了硫转化效率.
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