对于Ca2+和Zn2+可充电牙树脂复合材料的EDTA功能化中等二氧化 (mSiO2-EDTA)
Jiahui Huang1, Hongxia Zhang1, Xiangyu Zhang2
1Shanxi Key Laboratory of Biomedical Metal Materials, College of Materials Science and Engineering, Taiyuan University of Technology, 79 West Yingze Road, Taiyuan 030024, China.
概括
研究人员开发了可充电牙复合材料,使用乙二胺四酸 (EDTA) 接种的半孔SiO2 (mSiO2) 填充剂. 这些新型复合材料表明和离子的持续释放和可充电性,提供了一种对抗次要的有希望的策略.
科学领域:
- 材料科学 材料科学 材料科学
- 生物材料工程 生物材料工程
- 牙科材料 牙科材料
背景情况:
- 二次性仍然是恢复性牙科的一个重大挑战.
- 牙复合材料需要增强的性能,以改善寿命和患者的结果.
- 半孔二氧化 (mSiO2) 为药物输送和离子结合提供了一个多功能平台.
研究的目的:
- 为了合成乙烯基胺四酸 (EDTA) 修饰的中性二氧化 (mSiO2) 填料.
- 用于制造含有Ca2+和Zn2+离子的可充电牙科复合材料.
- 评估EDTA修改对牙科复合材料的性能和功能的影响.
主要方法:
- 通过化对mSiO2的EDTA功能化.
- 在mSiO2-EDTA上通过离子浸泡吸附Ca2+和Zn2+.
- 在牙科树脂矩阵中加入功能填充剂.
- 对离子释放,可充电性,再矿化,抗菌活性,机械性质和生物相容性的评估.
主要成果:
- 成功合成了mSiO2-EDTA和带离子粒子.
- 牙复合材料显示了Ca2+和Zn2+离子的持续释放和完全充电性.
- 释放的离子促进了矿化和抗菌活性.
- 修改EDTA并没有影响机械性能,光固化或生物相容性.
结论:
- 使用EDTA功能化的mSiO2填充剂开发了新的可充电牙复合材料.
- 这些复合材料表现出极好的离子释放和充电能力.
- 这些发现提出了一种潜在的策略,用于在牙科修复中抑制次要.
相关概念视频
EDTA: Auxiliary Complexing Reagents
1.2K
EDTA titrations are usually carried out in highly basic conditions, where the fully deprotonated form of EDTA, Y4−, actively complexes with the free metal ions in the solution. Several metal ions precipitate as hydrous oxide (hydroxides, oxides, or oxyhydroxides) under these conditions, lowering the concentration of free metal ions in the solution. For this reason, auxiliary complexing agents or ligands such as ammonia, tartrate, citrate, or triethanolamine are used in EDTA titrations to...
1.2K
EDTA: Chemistry and Properties
3.2K
Polydentate ligands are most widely used in complexometric titrations because they form more stable complexes with the metal ions than mono- or bidentate ligands due to the chelate effect. Examples of polydentate ligands are ethylenediaminetetraacetic acid (EDTA), crown ethers, and cryptands. The most important feature of optimal polydentate ligands is the ability to form 1:1 complexes in a single-step process. Amino carboxylic acid derivatives are frequently used as complexing agents. EDTA is...
3.2K
Masking and Demasking Agents
3.4K
EDTA titrations may necessitate masking and demasking agents to temporarily protect a particular metal ion in a mixture from the EDTA reaction. These agents facilitate the sequential analysis of the metal ions by forming stable complexes with some—but not all—metal ions during certain steps.
There are many masking agents, such as cyanide, fluoride, triethanolamine, thiourea, and 2,3-bis(sulfanyl)propan-1-ol (formerly 2,3-dimercapto-1-propanol), with the masking agent chosen based on...
There are many masking agents, such as cyanide, fluoride, triethanolamine, thiourea, and 2,3-bis(sulfanyl)propan-1-ol (formerly 2,3-dimercapto-1-propanol), with the masking agent chosen based on...
3.4K
Complexometric Titration: Ligands
2.2K
Different monodentate and polydentate ligands are used as complexing agents in complexometric titration reactions. The formation of complexes by mono- and bidentate ligands involves two or more intermediate steps, limiting their use as complexing agents. In comparison, polydentate ligands can form complexes with metal ions in a single-step process, facilitating sharper end points. This means polydentate ligands, such as amino carboxylic acid derivatives, are most commonly employed in...
2.2K
EDTA: Direct, Back-, and Displacement Titration
5.2K
The EDTA titration types for metal ion analysis include direct titration, back-titration, and replacement titration.
Direct titration involves buffering the metal ion solution to the desired pH and directly titrating with standard EDTA until the endpoint. The optimum pH ensures a large conditional formation constant of metal−EDTA and visibility of the free indicator color in the solution. In addition, auxiliary complexing reagents are used to prevent the precipitation of metal hydroxides...
Direct titration involves buffering the metal ion solution to the desired pH and directly titrating with standard EDTA until the endpoint. The optimum pH ensures a large conditional formation constant of metal−EDTA and visibility of the free indicator color in the solution. In addition, auxiliary complexing reagents are used to prevent the precipitation of metal hydroxides...
5.2K
EDTA: Indirect and Alkalimetric Titration
1.7K
Unlike direct titration, back-titration, and displacement titration, indirect titration is an EDTA titration method for quantifying anions. In the indirect titration method, anions are precipitated as their insoluble salts with excess metal ions. The filtrate containing the excess metal ions is directly titrated with standard EDTA until the endpoint is achieved. Another approach involves extracting the metal ion and back-titrating with standard EDTA to obtain the endpoint. In this way, the...
1.7K


