具有移动交叉连接点的共价适应网络.
Li Yang1, Wenbin Wang1, Yuanhao Wang1
1State Key Laboratory of Synergistic Chem-Bio Synthesis, Frontiers Science Center for Transformative Molecules, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, P.R. China.
Angewandte Chemie (International ed. in English)
|December 19, 2025
概括
我们开发了基于聚甲的共价适应性网络 (PRCANs),具有移动动态交叉链接. 与传统的CAN相比,这些PRCAN具有卓越的机械性能和明显较低的加工温度.
科学领域:
- 材料科学 材料科学 材料科学
- 聚合物化学 聚合物化学
- 可持续材料 可持续材料
背景情况:
- 联适应性网络 (CAN) 对可持续材料具有前景,但在平衡可加工性和机械性能方面面临挑战.
- 现有的CAN通常需要高加工温度,并表现出有限的机械弹性.
研究的目的:
- 引入一种新型的基于聚甲的CAN类 (PRCANs),利用移动动态交叉连接点.
- 调查移动动态交叉连接如何影响CAN中的机械性能和处理温度.
主要方法:
- 合成的PRCAN具有具有动态乙烯键的机械互锁轴.
- 将PRCAN的机械性能 (破裂时的延长,拉力强度,性) 和再加工特性与具有固定交叉连接的控制样本进行了比较.
主要成果:
- 与控制物相比,PRCANs显著提高了机械性能,破裂和拉伸强度的延伸是两倍,性是四倍以上.
- 在PRCAN中的移动交叉连接点减少了与对照组 (140°C30分钟) 相比,所需的处理温度 (110°C10分钟).
- 在PRCAN中移动动态共价键促进了在压力下有效的能量消散.
结论:
- 具有移动动态交叉连接的基于聚氨酸的CAN提供了一种可行的策略,以克服传统CAN的局限性.
- PRCANs为开发高性能,易于加工和可持续材料提供了一个新的平台.
相关概念视频
Network Covalent Solids
16.0K
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
16.0K
Contact-dependent Signaling
46.8K
Contact-dependent signaling, as the name suggests, requires that communicating cells be in direct contact with each other. This is achieved either through receptor-ligand interactions or by specialized cytoplasmic channels that allow the flow of small molecules between cells. In animal cells, channels called gap junctions facilitate contact-dependent signaling in certain tissues, whereas, plasmodesmata perform a similar function in plants.
Gap Junctions
In animal cells, gap junctions are formed...
Gap Junctions
In animal cells, gap junctions are formed...
46.8K
Covalently Linked Protein Regulators
2.0K
2.0K
Covalently Linked Protein Regulators
8.6K
Proteins can undergo many types of post-translational modifications, often in response to changes in their environment. These modifications play an important role in the function and stability of these proteins. Covalently linked molecules include functional groups, such as methyl, acetyl, and phosphate groups, and also small proteins, such as ubiquitin. There are around 200 different types of covalent regulators that have been identified.
These groups modify specific amino acids in a protein....
These groups modify specific amino acids in a protein....
8.6K
Ligand Binding and Linkage
5.4K
Allosteric proteins have more than one ligand binding site; the binding of a ligand to any of these sites influences the binding of ligands to the other sites. When a protein is allosteric, its binding sites are called coupled or linked. In the case of enzymes, the site that binds to the substrate is known as the active site and the other site is known as the regulatory site. When a ligand binds to the regulatory site, this leads to conformational changes in the protein that can influence...
5.4K
Ligand Binding and Linkage
3.9K
3.9K


