硫化物的结构和电化学进化 在性的进化反应过程中
Sina Haghverdi Khamene1,2, Noëlle van Dalen1, Mariadriana Creatore1,3
1Department of Applied Physics and Science Education, Eindhoven University of Technology, Eindhoven, the Netherlands.
ChemSusChem
|December 20, 2025
概括
在演化反应过程中,硫化转化为高度活跃的Ni3S2阶段,提高性能. 这种电化学激活,由硫洗驱动,随着时间的推移提高了催化剂的稳定性.
科学领域:
- 材料科学 材料科学 材料科学
- 电化学 电化学 电化学
- 催化剂是一种催化剂.
背景情况:
- 硫化是化演化反应 (HER) 的经济有效的电催化剂.
- 对于长期HER运行期间硫化物的结构改变的了解有限.
- 研究这些转换对于开发稳定和活跃的HER催化剂至关重要.
研究的目的:
- 研究各种硫化晶体催化剂的电解后结构和电化学演变.
- 了解转变的基本机制及其对 HER 性能的影响.
- 在初始激活后评估硫化催化剂的长期稳定性.
主要方法:
- 循环电压测量 (CV) 循环和恒流偏振被用来诱导HER.
- 拉曼光谱法被用来确认结构相变.
- 进行了电化学表面积,电荷转移特性和运动分析.
主要成果:
- 所有硫化物在500次CV扫描后转化为Ni3S2,这是HER活性最强的阶段.
- 这种转换改善了电化学表面积和电荷转移特性.
- 硫泄漏被确定为重组和激活的主要驱动因素,主要发生在初始操作期间.
结论:
- 硫化在HER过程中经历电化学激活过程,转化为Ni3S2阶段.
- 这种激活通过转移速度决定步骤并改善催化剂特性来增强HER动力学.
- 硫溶是硫HER催化剂初始激活和随后稳定的一个关键因素.
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