石表面能量的起源及其湿透性
Zilong Liu1,2, Xue Li2,3, Shiming Wei1,2
1State Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum (Beijing), Beijing 102249, China.
Langmuir : the ACS journal of surfaces and colloids
|December 22, 2025
概括
这项研究揭示了表面能量如何决定石的能量.
科学领域:
- 矿物表面科学 矿物表面科学
- 固体液体界面现象 固体液体界面现象
- 地质化学 地质化学
背景情况:
- 石的异构性质在各种科学领域至关重要.
- 了解石异性背后的物理机制是有限的.
- 固体-液体接口行为是矿物加工和岩石力学中的关键.
研究的目的:
- 为了建立表面能量和石的物理性质之间的定量关系.
- 为了研究石的异构表面特性,特别是 (104) 表面.
- 探索水和盐度对石表面能量和湿度的影响.
主要方法:
- 开发了一种量化模型,将表面断裂键密度 (Db) 和层间距 (d) 与表面能量 (γdry) 相关联.
- 分析了异性质的表面特性,以确定最常见的裂纹表面.
- 通过接触角度测量和电荷转移分析,研究了水覆盖面和盐度的影响.
主要成果:
- 确定了方程 γdry = 0.021Db - 1.036d + 0.77 对于石的表面能量.
- 鉴定出 (104) 石表面是最常见的裂变表面,因为表面能量较低.
- 发现,增加水覆盖率降低了表面能量,盐离子争夺水吸附点.
结论:
- 开发的模型提供了一种新的方法来评估石的表面稳定性和反应性.
- 提供了对石表面水吸附和湿透机制的洞察.
- 这项研究促进了对矿物表面科学和固体-液体界面相互作用的理解.
相关概念视频
Surface Tension and Surface Energy
2.9K
When a paint brush is immersed in water, the bristles wave freely inside the water. When it is taken out, the bristles stick together. The reason behind this effect is surface tension.
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
2.9K
Surface Tension, Capillary Action, and Viscosity
32.4K
Surface Tension
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
The various IMFs between identical molecules of a substance are examples of cohesive forces. The molecules within a liquid are surrounded by other molecules and are attracted equally in all directions by the cohesive forces within the liquid. However, the molecules on the surface of a liquid are attracted only by about one-half as many molecules. Because of the unbalanced molecular attractions on the surface molecules, liquids contract to form a shape that minimizes the number...
32.4K
Surface Tension of Fluid
1.3K
Surface tension is a fundamental property of fluids, occurring at the boundary between a liquid and a gas or between two immiscible liquids. This phenomenon arises from the cohesive forces between molecules at the fluid's surface, creating an effect similar to a stretched elastic membrane. Inside each fluid, molecules are equally attracted in all directions by neighboring molecules, but surface molecules experience a net inward force, resulting in surface tension.
Surface tension varies...
Surface tension varies...
1.3K
Fineness of Cement
432
The fineness of cement directly influences the rate of hydration, as the hydration begins at the surface of the cement particles. In addition to hydration, the fineness of cement is vital for various properties of concrete including workability, gypsum requirement, and long-term behavior. The fineness of cement is represented in terms of the specific surface of cement which is typically measured in square meters per kilogram, with several methods available for this determination.
Direct...
Direct...
432
Contact Angle
17.8K
When a solid is dipped inside a liquid, the liquid surface becomes curved near the contact. For some solid–liquid interfaces, the liquid is pulled up along the solid, while for others, the liquid surface is convex or depressed near the solid surface. This phenomenon can be explained using the concept of cohesive and adhesive forces.
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive...
The adhesive force is the molecular force between molecules of different materials, that is, between the molecules of the solid and the liquid. The cohesive...
17.8K
Cohesion
58.1K
Cohesion is the attraction between molecules of the same type, such as water molecules. Water molecules have an overall neutral charge but are polar molecule. An oxygen atom in one water molecule has a partial negative charge that can bind to a hydrogen atom with a partial positive charge in a second water molecule, forming a hydrogen bond. Each water molecule can form up to four hydrogen bonds with other water molecules. Hydrogen bonds are responsible for water's cohesive nature.
On a...
On a...
58.1K


